Enhanced stability of charge-order in underdoped Bi0.75Sr0.25MnO3

被引:27
作者
Frontera, C
García-Muñoz, JL
Ritter, C
Mañosa, L
Capdevila, XG
Calleja, A
机构
[1] CSIC, Inst Ciencia Mat Barcelona, Dept Magnet & Superconducting Mat, E-08193 Bellaterra, Spain
[2] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
[3] Univ Barcelona, Fac Fis, Dept Estructura & Constituents Mat, E-08028 Barcelona, Spain
[4] Univ Barcelona, Fac Quim, Dept Engn Quim & Met, E-08028 Barcelona, Spain
关键词
electron-phonon interaction; heat capacity; X-ray scattering; Newton scattering;
D O I
10.1016/S0038-1098(02)00660-9
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We report that the charge-ordered phase of Bi0.75Sr0.25MnO3 presents a transition temperature T-CO similar or equal to600 K, well above the ordering temperature in half-doped Bi0.50Sr0.50MnO3 (T-CO similar or equal to 525 K). Magnetization, calorimetry, and neutron diffraction measurements evidence that, in underdoped Bi0.75Sr0.25MnO3, an off-stoichiometry corresponding to a Mn3+/Mn4+ ratio of 3 increases T-CO by similar to 75 K with respect to half-doping. This unusual feature confirms the active role of Bi in this family, the only known manganites presenting charge order well above room temperature. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:277 / 280
页数:4
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