Comparative analyses of biodiesel produced from jatropha and neem seed oil using a gas chromatography-mass spectroscopy technique

被引:23
作者
Kaisan, M. U. [1 ]
Abubakar, S. [1 ]
Ashok, B. [2 ]
Balasubramanian, Dhinesh [3 ]
Narayan, S. [4 ]
Grujic, Ivan [5 ]
Stojanovic, Nadica [5 ]
机构
[1] Ahmadu Bello Univ, Zaria, Nigeria
[2] VIT Univ, Vellore, Tamil Nadu, India
[3] Mepco Schlenk Engn Coll, Sivakasi, India
[4] Qassim Univ, Mech Engn Dept, Buraydah, Saudi Arabia
[5] Univ Kragujevac, Fac Engn, Kragujevac, Serbia
来源
BIOFUELS-UK | 2021年 / 12卷 / 07期
关键词
Biodiesel; jatropha; neem; gas chromatography; mass spectroscopy; FUEL; L; TRANSESTERIFICATION; BLENDS;
D O I
10.1080/17597269.2018.1537206
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Biodiesel from jatropha, neem and cottonseed were produced and their compositions were analyzed using gas chromatography-mass spectroscopy. The results revealed that the jatropha, neem and cottonseed oils are reliable sources of biodiesel and are renewable, and hence have a potential to partially meet energy demands in an eco-friendly manner. The biodiesels produced from jatropha contained 91.97% methyl ester, and that produced from neem contained 70.2% methyl ester, whereas that produced from cotton contained 89.75% methyl ester.The greater proportion of prolific ester in the jatropha biodiesel is mono-saturated methyl octa-decanoate which contributes 53.44% by volume. This ester has the tendency of assigning stability to biodiesel. For neem-based biodiesel, the profile evaluation revealed that octadecanoic acid methyl ester is the dominant compound in the mixture with 54.69% by volume. For cotton, the profile revealed that the methyl octadecenoate (C19H36O2) is the predominant compound in the mixture, having the highest percentage of 17.72%. The physico-chemical analyses of the three biodiesels has indicated that the three conform with the American Society for Testing and Materials (ASTM) standards for specific gravity, viscosity, acid value, cold flow properties and sulfur content, and hence are suitable for use in compression ignition engines. Statistical analyses confirmed that there was no significant difference between the experimental values of all the physico-chemical properties investigated; therefore, the experimental data is validated.
引用
收藏
页码:757 / 768
页数:12
相关论文
共 49 条
[11]  
Bugaje IM., 2014, BIOFUELS PRODUCTION
[12]  
Caprita R, 2005, AGROALIMENTARY PROCE, V11, P179
[13]   Biodiesel as alternative fuel: Experimental analysis and energetic evaluations [J].
Carraretto, C ;
Macor, A ;
Mirandola, A ;
Stoppato, A ;
Tonon, S .
ENERGY, 2004, 29 (12-15) :2195-2211
[14]   Waste Cooking Oil as an Alternate Feedstock for Biodiesel Production [J].
Chhetri, Arjun B. ;
Watts, K. Chris ;
Islam, M. Rafiqul .
ENERGIES, 2008, 1 (01) :3-18
[15]  
Coronado M, 2009, APPL ENG AGRIC, V25, P217
[16]   Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods [J].
Demirbas, A .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2005, 31 (5-6) :466-487
[17]   Biofuels sources, biofuel policy, biofuel economy and global biofuel projections [J].
Demirbas, Ayhan .
ENERGY CONVERSION AND MANAGEMENT, 2008, 49 (08) :2106-2116
[18]  
EIA, 2013, THE FULL REPORT
[19]  
Enwerenmadu CC., 2014, J IND MECH ENG, V2, P15
[20]  
Gangadhara R., 2016, STUDIES OPTIMIZATION, P59