Assembly of Four Kinds of Cages into Porous Metal-Organic Framework for Selective Sorption of Light Hydrocarbons

被引：11
作者：
Wang, Fei [1 ]
Fu, Hong-Ru [1 ]
Hou, Duan-Chuan [1 ]
Zhang, Jian [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2014年 / 14卷 / 12期
关键词：
ROOM-TEMPERATURE; SEPARATION; ADSORPTION; ETHYLENE; METHANE; ETHANE; PROPYLENE; MOLECULES; CHEMISTRY; ACETYLENE;
D O I：
10.1021/cg5013318
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The direct assembly of four kinds of cages by face-sharing and edge-sharing modes with Zn-3(mu 3-OH)(H2O)(COO)(4) units and organic ligands generates a porous framework material including 3D channels, which shows high adsorption enthalpy of C3H8 (35 kJ/mol) and excellent adsorption selectivity of C3H8 over CH4 under ambient conditions.
引用
收藏
页码：6467 / 6471
页数：5
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