Recent Advances in Transition-Metal-Catalyzed Reactions of N-Tosylhydrazones

被引：43
作者：
Radolko, Jan [1 ]
Ehlers, Peter [1 ,2 ]
Langer, Peter [1 ,2 ]
机构：
[1] Univ Rostock, Inst Chem, A Einstein Str 3a, D-18059 Rostock, Germany
[2] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 15期
关键词：
Bamford-Stevens reaction; Catalysis; Cross-Coupling reactions; Diazo Compounds; Metal Carbenes; Tosylhydrazones; CROSS-COUPLING REACTIONS; ONE-POT REACTION; CARBENE MIGRATORY INSERTION; CSP(2)-N BOND FORMATION; ARYL HALIDES SYNTHESIS; TERMINAL ALKYNES; EFFICIENT SYNTHESIS; CASCADE REACTIONS; TOSYL HYDRAZONES; INTRAMOLECULAR CYCLOPROPANATION;
D O I：
10.1002/adsc.202100332
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Transition-metal-catalyzed reactions of N-tosylhydrazones provide a convenient access to various molecules by novel carbon-carbon or carbon-heteroatom bond formations via carbene-type intermediates. The present review highlights recent developments in the field emphasize of the employment of different transition metals as catalysts, synthetic applications, mechanistic studies and use in domino and multicomponent reactions.
引用
收藏
页码：3616 / 3654
页数：39
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