Surface polarization in interfacial monolayer and SHG-MDC spectroscopy

被引：0
|
作者：
Iwamoto, M [1 ]
Manaka, T [1 ]
Tojima, A [1 ]
机构：
[1] Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528552, Japan
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2004年 / 424卷
基金：
英国医学研究理事会; 英国惠康基金;
关键词：
D O I：
10.1080/15421400490505785
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Optical Second Harmonic Generation (SHG) and Maxwell displacement (MDC) spectroscopy for the exploration of organic monolayer film is described. MDC and SHG are ascribed to tire surface spontaneous and non-linear polarization of the monolayers due to symnetry breaking, respectively. It is shown. that the ShG-MDC measurement, cow be used for the study] of the orientational orders. In order to show lite effect of the SHG-MDC spectroscopy, the, dielectric polarization of monolayer with C-infinity-symmetry is theoretically analyzed with a simple rod-molecule model, and the surface polarization induced in the monolayer is expressed using orientational order parameters. The SHG and MDC generated from mesogenic liquid crystal (LC) monolayers are shown, and discussed based on the developed theory.
引用
收藏
页码：7 / 15
页数：9
相关论文
共 50 条
  • [21] Surface chemistry and in situ spectroscopy of a lysozyme langmuir monolayer
    Thakur, Garima
    Wang, Chengshan
    Leblanc, Roger A.
    LANGMUIR, 2008, 24 (09) : 4888 - 4893
  • [22] SURFACE-PLASMON SPECTROSCOPY OF ORGANIC MONOLAYER ASSEMBLIES
    POCKRAND, I
    SWALEN, JD
    GORDON, JG
    PHILPOTT, MR
    SURFACE SCIENCE, 1978, 74 (01) : 237 - 244
  • [23] Monolayer frustration contributions to surface and interfacial tensions: Explanation of surfactant superspreading
    Kabalnov, A
    LANGMUIR, 2000, 16 (06) : 2595 - 2603
  • [24] Polarization modulation spectroscopy of surface plasmon resonance
    Berezhinsky, L. J.
    Maksimenko, L. S.
    Matyash, I. E.
    Rudenko, S. P.
    Serdega, B. K.
    OPTICS AND SPECTROSCOPY, 2008, 105 (02) : 257 - 264
  • [25] POLARIZATION SPECTROSCOPY AND ION-SURFACE INTERACTION
    BERRY, HG
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1977, 22 (03): : 274 - 274
  • [26] Exploiting polarization in nonlinear optical surface spectroscopy
    Simpson, GJ
    Plocinik, RM
    NANOPHOTONIC MATERIALS, 2004, 5510 : 97 - 106
  • [27] Polarization modulation spectroscopy of surface plasmon resonance
    L. J. Berezhinsky
    L. S. Maksimenko
    I. E. Matyash
    S. P. Rudenko
    B. K. Serdega
    Optics and Spectroscopy, 2008, 105 : 257 - 264
  • [28] Polarization Spectroscopy of Anisotropic Plasmons in Self-Oriented Nanoclusters of Gold on Monolayer of Nitrogen Atoms Chemisorbed at GaAs(001) Surface
    Berkovits, Vladimir L.
    Kosobukin, Vladimir A.
    Ulin, Vladimir P.
    Alekseev, Prokhor A.
    Soldatenkov, Fedor Yu
    Levitskii, Vladimir S.
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2022, 259 (01):
  • [29] THE MONOLAYER CO ADSORBED ON MGO(100) DETECTED BY POLARIZATION INFRARED-SPECTROSCOPY
    HEIDBERG, J
    KANDEL, M
    MEINE, D
    WILDT, U
    SURFACE SCIENCE, 1995, 331 : 1467 - 1472
  • [30] Effects of the interfacial polarization on tunneling in surface coupled quantum dots
    Virk, Kuljit S.
    Reichman, David R.
    Hybertsen, Mark S.
    PHYSICAL REVIEW B, 2012, 86 (16):
12345