Interaction between Pt(IV) and Pd(II) chloro complexes in solution and on the γ-Al2O3 surface

被引：18
作者：
Bel'skaya, O. B. [1 ]
Gulyaeva, T. I. [1 ]
Arbuzov, A. B. [1 ]
Duplyakin, V. K. [1 ]
Likholobov, V. A. [1 ]
机构：
[1] Russian Acad Sci, Inst Hydrocarbon Proc, Siberian Branch, Omsk 644040, Russia
来源：
KINETICS AND CATALYSIS | 2010年 / 51卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
NORMAL-HEXANE DEHYDROCYCLIZATION; BIMETALLIC CATALYSTS; PLATINUM CATALYSTS; PALLADIUM; PD; HYDROGEN; REDUCTION; AROMATICS; OXIDATION; SORPTION;
D O I：
10.1134/S0023158410010179
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The conversions of a mixture of platinum(IV) and palladium(II) chloro complexes in aqueous solution and on the gamma-Al2O3 surface at 25-150A degrees C are reported. Heat treatment can initiate interaction between the complexes, both dissolved and adsorbed. The hydrolysis of the chloroplatinate ion is accelerated by the palladium chloro complex, whose composition remains unchanged.
引用
收藏
页码：105 / 112
页数：8
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