An organophotoredox-catalyzed C(sp2)-N cross coupling reaction of cyclic aldimines with cyclic aliphatic amines

被引：17

作者：

Liu, Xue ^{[1
]}

Wang, Jingjing ^{[2
]}

Wu, Ziyan ^{[2
]}

Li, Feng ^{[2
]}

Gao, Kexin ^{[2
]}

Peng, Fanyang ^{[2
]}

Wang, Junjie ^{[2
]}

Shen, Renzeng ^{[2
]}

Zhou, Yao ^{[3
]}

Liu, Lantao ^{[1
,2
]}

机构：

[1] Zhengzhou Univ, Coll Chem, Zhengzhou 450052, Henan, Peoples R China

[2] Shangqiu Normal Univ, Coll Chem & Chem Engn, Henan Key Lab Biomol Recognit & Sensing, Shangqiu 476000, Henan, Peoples R China

[3] Hubei Normal Univ, Coll Chem & Chem Engn, Hubei Key Lab Pollutant Anal & Reuse Technol, Huangshi 435002, Hubei, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 16期

基金：

中国国家自然科学基金;

关键词：

N BOND-FORMATION; C-H AMINATION; DECARBOXYLATIVE MANNICH REACTION; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC ARYLATION; 5+2 CYCLOADDITION; FUNCTIONALIZATION; SULFONYLIMINES; CONSTRUCTION; STRATEGIES;

D O I：

10.1039/d1ob00223f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An organophotocatalyzed C(sp(2))-H/N-H cross-dehydrogenative coupling of cyclic aldimines with aliphatic amines has been developed, which represents the first example of visible-light-induced C-H amination of N-sulfonylated imines. This methodology enables the streamline assembly of amine derivatives via radical mediated C-N bond formation. The current protocol features transition-metal-free, mild conditions, good functional group tolerance and good yields.

引用

页码：3595 / 3600

页数：6

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