Examining the nature of network formation during epoxy polymerisation initiated with ionic liquids

A commercial diglycidyl ether of bisphenol A monomer (Baxxores (TM) ER 2200, eew 182 g/mole, DGEBA) is thermally polymerized in the presence of an ionic liquid, 1-ethyl-3-methylimidazolium acetate at a variety of loadings (5-45 wt %). The loss modulus data for cured samples, containing 5 wt % initiator, display at least two thermal transitions and the highest storage modulus occurs in the sample that has been cured for the shortest time at the lowest temperature. Samples that are exposed to higher temperatures (140, 150 degrees C) yield more heterogenous networks, whereas following exposure to a much shorter/lower temperature cure schedule (80 degrees C) exhibits a considerably higher damping ability than the other samples, coupled with a lower glass transition temperature. Differential scanning calorimetry reveals that the latter sample achieves a conversion of 95%, while crosslink densities for the DGEBA samples containing 5 wt % and 15 wt % are respectively 9.5 x 10(-3)mol. dm(-3) and 1.2 x 10(-3)mol. dm(-3 )(when cured to 80 degrees C) and 2.0 x 10(-2)mol. dm(-3) and 2.4 x 10(-3)mol. dm(-3) (when cured to 140 degrees C). (C) 2018 Elsevier Ltd. All rights reserved.