Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

被引：13
作者：
Fang, Zeguo
Al-Maharik, Nawaf
Slawin, Alexandra M. Z.
Hl, Michael Bu
O'Hagan, David [1 ]
机构：
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 29期
基金：
英国工程与自然科学研究理事会;
关键词：
SPIN COUPLING-CONSTANTS; DENSITY FUNCTIONALS; BASIS-SETS; FLUORINE; BOND; CYCLOHEXANE; TRIFLUORIDE;
D O I：
10.1039/c6cc01348a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.
引用
收藏
页码：5116 / 5119
页数：4
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