Heterometallic CuII-LnIII complexes: Single molecule magnets and magnetic refrigerants

被引：70

作者：

Dey, Atanu ^{[1
]}

Bag, Prasenjit ^{[1
]}

Kalita, Pankaj ^{[1
]}

Chandrasekhar, Vadapalli ^{[1
,2
]}

机构：

[1] Tata Inst Fundamental Res Hyderabad, Hyderabad 500046, India

[2] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

COORDINATION CHEMISTRY REVIEWS | 2021年 / 432卷

关键词：

Heterometallic J(Cu)(II) -(III)(Ln) complexes; Ferromagnetic interaction; Single molecule magnets; Magnetocaloric effect; Single chain magnets; MONONUCLEAR LANTHANIDE COMPLEXES; HEPTANUCLEAR CU(5)LN(2) LN; METAL-ORGANIC FRAMEWORK; II/GD-III COUPLE; CU-II; GD-III; TB-III; CRYSTAL-STRUCTURE; SLOW RELAXATION; EXCHANGE INTERACTIONS;

D O I：

10.1016/j.ccr.2020.213707

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated extensively for the past few years realizing the role of exchange interaction to minimize the QTM effect. In this context, heterometallic complexes particularly containing Cu-II-Ln(III) have encompassed a pivotal role due to the ferromagnetic exchange interaction. Herein we review the Cu/Ln complexes that exhibit single molecule magnet (SMM)/magnetocaloric effect (MCE) in a comprehensive way. (C) 2020 Elsevier B.V. All rights reserved.

引用

页数：68

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