Sorption concentration of organic compounds on hydrophobic sorbents in dynamic conditions

被引:0
|
作者
Filippov, OA [1 ]
Tikhomirova, TI [1 ]
Badun, GA [1 ]
Tsizin, GI [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2003年 / 77卷 / 06期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It was shown that the process of dynamic sorption concentration of organic compounds of different natures on hydrophobic sorbents can be described in terms of the linear model of sorption dynamics. Using the model, the thermodynamic (distribution coefficient) and kinetic (mass-transfer coefficient) parameters of sorption were calculated. Optimum conditions were determined for the concentration of phenol on highly crosslinked polystyrene and 4-nitrobenzaldehyde N,N-dimethylhydrazone on silica chemically modified with hexadecyl groups from aqueous solutions.
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页码:981 / 986
页数:6
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