Potassium zinc borate, KZnB3O6

被引：43

作者：

Wu, Yang ^{[1
]}

Yao, Ji-Yong ^{[1
]}

Zhang, Jian-Xiu ^{[1
]}

Fu, Pei-Zhen ^{[1
]}

Wu, Yi-Cheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystal & Laser Technol, Beijing 100190, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

基金：

中国国家自然科学基金;

关键词：

HIGH-PRESSURE PREPARATION; CRYSTAL-STRUCTURE; RE; DY;

D O I：

10.1107/S1600536810015175

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, KZnB3O6 contains a remarkable [B6O12](6-) group ((1) over bar symmetry) formed by two rings linked by edge-sharing BO4 tetrahedra, a feature that has only been observed previously under high pressure conditions. These borate groups are connected through distorted ZnO4 tetrahedra in edge-shared pairs ((1) over bar symmetry), forming a three-dimensional network whose cavities are filled by K+ cations.

引用

页码：I45 / U212

页数：15

共 14 条

[1]

[Anonymous], 2008, CRYSTALCLEAR

[2] Syntheses, band structures and optical properties of Zn3B2O6 and KZn4B3O9 [J].