Electrical and mechanical properties of carbon nanotube/ultrahigh-molecular-weight polyethylene composites prepared by a filler prelocalization method

被引:85
作者
Mierczynska, A.
Mayne-L'Hermite, M.
Boiteux, G.
Jeszka, J. K. [1 ]
机构
[1] Tech Univ Lodz, Dept Mol Phys, PL-90924 Lodz, Poland
[2] CEA Saclay, SPAM, DRECAM, DSM,CNRS,URA 2453,Lab Francis Perrin, F-91191 Gif Sur Yvette, France
[3] UCB Lyon 1, Lab Mat Polymers & Biomat, Villeurbanne, France
[4] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland
关键词
mechanical properties; nanocomposites; sintering;
D O I
10.1002/app.26044
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The method of preparation and the properties of conductive composites of ultrahigh-molecular-weight polyethylene with different carbon nanotubes (CNTs) as conductive fillers are presented. The composites were prepared through the covering of the surface of polyethylene granules with CNTs and sintering under optimized conditions. The electrical and mechanical properties of the composites were investigated as functions of the CNT concentration and CNT dispersion process for several kinds of single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs). The CNTs were not uniformly dispersed in the composites but were prelocalized on the granule boundaries, very efficiently forming conductive networks. It was, however, critically important to ensure the good dispersion of the nanotubes in the microscale, and this was performed by sonication in sol vents before dry mixing. Ultralow percolation thresholds were obtained: 0.095 wt % for SWCNTs and 0.05 wt % for MWCNTs (ca. 0.045 vol % for SWCNTs and 0.021 vol % for MWCNTs). The critical exponents were higher than those for uniformly dispersed conductive particles: 2.2 and 2.6 for SWCNTs and for MWCNTs, respectively. The mechanical properties of the composites were also strongly modified by the presence of CNTs. The modulus and ultimate strength increased by about 100% with 2% CNTs. The elongation at break decreased but was still about 500-1000%. Near the electrical percolation threshold, the mechanical properties were not significantly modified. (C) 2007 Wiley Periodicals, Inc.
引用
收藏
页码:158 / 168
页数:11
相关论文
共 27 条
[1]   DC and AC conductivity of carbon nanotubes-polyepoxy composites [J].
Barrau, S ;
Demont, P ;
Peigney, A ;
Laurent, C ;
Lacabanne, C .
MACROMOLECULES, 2003, 36 (14) :5187-5194
[2]   Conductive composites of UHMWPE and ceramics based on the segregated network concept [J].
Bouchet, J ;
Carrot, C ;
Guillet, J ;
Boiteux, G ;
Seytre, G ;
Pineri, M .
POLYMER ENGINEERING AND SCIENCE, 2000, 40 (01) :36-45
[3]   Electrical properties of polymer composites prepared by sintering a mixture of carbon black and ultra-high molecular weight polyethylene powder [J].
Chan, CM ;
Cheng, CL ;
Yuen, MMF .
POLYMER ENGINEERING AND SCIENCE, 1997, 37 (07) :1127-1136
[4]  
De Gennes PG., 1979, SCALING CONCEPTS POL
[5]  
DRESSELHAUS MS, 1996, SCI FULLERENS CARBON
[6]   Carbon black-filled immiscible blends of poly(vinylidene fluoride) and high density polyethylene: Electrical properties and morphology [J].
Feng, JY ;
Chan, CM .
POLYMER ENGINEERING AND SCIENCE, 1998, 38 (10) :1649-1657
[7]  
GLORY J, 2007, J NANOSCI NANOTECHNO
[8]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[9]   Production of aqueous colloidal dispersions of carbon nanotubes [J].
Jiang, LQ ;
Gao, L ;
Sun, J .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 260 (01) :89-94
[10]  
Kaiser AB, 1999, SYNTHETIC MET, V103, P2547, DOI 10.1016/S0379-6779(98)00222-7