Structural studies on drop-cast film based on functionalized gold nanoparticles network: The effect of thermal treatment

被引:15
作者
Fontana, Laura [1 ]
Fratoddi, Ilaria [1 ]
Venditti, Iole [1 ]
Ksenzov, Dmitriy [2 ]
Russo, Maria Vittoria [1 ]
Grigorian, Souren [2 ]
机构
[1] Univ Roma La Sapienza, Dept Chem, Ple A Moro 5, I-00185 Rome, Italy
[2] Univ Siegen, Dept Phys, Walter Flex Str 3, D-57072 Siegen, Germany
关键词
Gold nanoparticles network; In situ annealing; GIXD; Nanoparticles reorganization; ADSORBATES; MONOLAYER; POLYMERS; PT(II); ARRAY;
D O I
10.1016/j.apsusc.2016.02.029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present work the role of the thermal treatment on the reorganization of gold nanoparticles (AuNPs) functionalized with a pi-conjugated dithiol ligand, namely 9,9-didodecyl-2,7-bis-thiofluorene, is studied by grazing incidence X-ray diffraction technique. For a detailed investigation of the structural changes and reorganization occurring in the AuNPs network and of the monitoring of complex interactions between nanoparticles, the line profiles are analyzed in out-of-plane and in-plane directions. The obtained data support the idea of the formation of a uniform network of nanoparticles that after annealing are extended from hexagonal to cubic arrangement. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:115 / 119
页数:5
相关论文
共 53 条
[1]  
[Anonymous], 1992, Critical Phenomena at Surfaces and Interfaces
[2]   Structure and Morphology of Organic Semiconductor-Nanoparticle Hybrids Prepared by Soft Deposition [J].
Banerjee, R. ;
Novak, J. ;
Frank, C. ;
Girleanu, M. ;
Ersen, O. ;
Brinkmann, M. ;
Anger, F. ;
Lorch, C. ;
Dieterle, J. ;
Gerlach, A. ;
Drnec, J. ;
Yu, S. ;
Schreiber, F. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (09) :5225-5237
[3]   NEXAFS study of a Pt-containing rod-like organometallic polymer (Pt-DEBP): molecular orientation onto HOPG, Au/Si(111), Cr/Si(111) and Si(111) surfaces [J].
Battocchio, C ;
Fratoddi, I ;
Russo, MV ;
Polzonetti, G .
CHEMICAL PHYSICS LETTERS, 2004, 400 (4-6) :290-295
[4]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[5]   Dielectric Relaxations of Ionic Thiol-Coated Noble Metal Nanoparticles in Aqueous Solutions: Electrical Characterization of the Interface [J].
Cametti, C. ;
Fratoddi, I. ;
Venditti, I. ;
Russo, M. V. .
LANGMUIR, 2011, 27 (11) :7084-7090
[6]   Multidentate Adsorbates for Self-Assembled Monolayer Films [J].
Chinwangso, Pawilai ;
Jamison, Andrew C. ;
Lee, T. Randall .
ACCOUNTS OF CHEMICAL RESEARCH, 2011, 44 (07) :511-519
[7]   Role of nanostructured polymers on the improvement of electrical response-based relative humidity sensors [J].
Fratoddi, I. ;
Bearzotti, A. ;
Venditti, I. ;
Cametti, C. ;
Russo, M. V. .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 225 :96-108
[8]   Gold nanoparticles and gold nanoparticle-conjugates for delivery of therapeutic molecules. Progress and challenges [J].
Fratoddi, I. ;
Venditti, I. ;
Cametti, C. ;
Russo, M. V. .
JOURNAL OF MATERIALS CHEMISTRY B, 2014, 2 (27) :4204-4220
[9]   Nanostructured polymetallaynes of controlled length:: Synthesis and characterization of oligomers and polymers from 1,1′-bis-(ethynyl)4,4′-biphenyl bridging Pt(II) or Pd(II) centers [J].
Fratoddi, Ilaria ;
Battocchio, Chiara ;
Groia, Alessandra L. ;
Russo, Maria V. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (15) :3311-3329
[10]   Chemiresistive polyaniline-based gas sensors: A mini review [J].
Fratoddi, Ilaria ;
Venditti, Iole ;
Cametti, Cesare ;
Russo, Maria Vittoria .
SENSORS AND ACTUATORS B-CHEMICAL, 2015, 220 :534-548