Structure-related emission spectrometric analysis of the chemiluminescence of catechins, theaflavins and anthocyanins

被引:21
作者
Miyazawa, T [1 ]
Nakagawa, K [1 ]
机构
[1] Tohoku Univ, Fac Agr, Dept Appl Biol Chem, Sendai, Miyagi 9818555, Japan
关键词
catechins; theaflavins; anthocyanins; chemiluminescence; emission spectrometry;
D O I
10.1271/bbb.62.829
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
This study for the first time achieved an emission spectrometric analysis of the chemiluminescence of flavonoids in the presence of hydrogen peroxide, acetaldehyde and horseradish peroxidase, and revealed that the maximum emission wavelengths (Emax) strictly differ among catechins (:Emax 630 nm), theaflavins (Emax 690 nm) and anthocyanins (Emax 675 nm) according to their chemical structures. This technique enabled the direct incorporation of dietary tea catechin into rat intestinal mucosal cells to be spectrometrically confirmed.
引用
收藏
页码:829 / 832
页数:4
相关论文
共 7 条
[1]   Review of the biology of quercetin and related bioflavonoids [J].
Formica, JV ;
Regelson, W .
FOOD AND CHEMICAL TOXICOLOGY, 1995, 33 (12) :1061-1080
[2]  
Kandaswami C., 1997, P174
[3]   Inhibition of mucosal lipid hyperoxidation by green tea extract in 1,2-dimethylhydrazine-induced rat colonic carcinogenesis [J].
Matsumoto, H ;
Yamane, T ;
Inagake, M ;
Nakatani, H ;
Iwata, Y ;
Takahashi, T ;
Nishimura, H ;
Nishino, H ;
Nakagawa, K ;
Miyazawa, T .
CANCER LETTERS, 1996, 104 (02) :205-209
[4]  
Nakagawa K, 1997, J NUTR SCI VITAMINOL, V43, P679, DOI 10.3177/jnsv.43.679
[5]   Chemiluminescence high-performance liquid chromatographic determination of tea catechin, (-)-epigallocatechin 3-gallate, at picomole levels in rat and human plasma [J].
Nakagawa, K ;
Miyazawa, T .
ANALYTICAL BIOCHEMISTRY, 1997, 248 (01) :41-49
[6]   Dose-dependent incorporation of tea catechins, (-)-epigallocatechin-3-gallate and (-)-epigallocatechin, into human plasma [J].
Nakagawa, K ;
Okuda, S ;
Miyazawa, T .
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY, 1997, 61 (12) :1981-1985
[7]   CHEMILUMINESCENCE OF BENZOIC AND CINNAMIC-ACIDS, AND FLAVONOIDS IN THE PRESENCE OF ALDEHYDE AND HYDROGEN-PEROXIDE OR HYDROXYL RADICAL BY FENTON REACTION [J].
YOSHIKI, Y ;
OKUBO, K ;
ONUMA, M ;
IGARASHI, K .
PHYTOCHEMISTRY, 1995, 39 (01) :225-229