Agro-industrial residues as low-price feedstock for diesel-like fuel production by thermal cracking

被引:55
作者
Santos, Andre L. F. [1 ]
Martins, Danilo U. [1 ]
Iha, Osvaldo K. [1 ]
Ribeiro, Rafael A. M. [1 ]
Quirino, Rafael L. [1 ]
Suarez, Paulo A. Z. [1 ]
机构
[1] Univ Brasilia, Inst Quim, Lab Mat & Combustiveis, BR-70910970 Brasilia, DF, Brazil
关键词
Pyrolysis; Biofuels; Fatty waste feedstock; ACROCOMIA-SCLEROCARPA M; VEGETABLE-OILS; SOYBEAN OIL; BIODIESEL PRODUCTION; ANIMAL FATS; PYROLYSIS; ACID; ESTERS; TRANSESTERIFICATION; TRIGLYCERIDES;
D O I
10.1016/j.biortech.2010.02.100
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Pyrolysis of industrial fatty wastes (soybean soapstock, beef tallow, and poultry industry waste) was carried out in the absence of catalysts. in all cases, organic mixtures of hydrocarbons and oxygenated compounds were obtained. These mixtures were distilled and diesel-like fractions were isolated and characterized by GC-FID. GC-MS and FT-IR, showing the formation of olefins, paraffins, and some oxygenated compounds such as carboxylic acids and esters. The main physical-chemical properties of those isolated diesel-like fuels (density, viscosity, distillation curve, carbon residue, copper corrosion test, cetane index, cold finger plugging point, acid index and heating value) were determined using ASTM standard methods and matched the Brazilian specification for diesel fuel. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6157 / 6162
页数:6
相关论文
共 32 条
[1]   New multi-phase catalytic systems based on tin compounds active for vegetable oil transesterificaton reaction [J].
Abreu, FR ;
Alves, MB ;
Macêdo, CCS ;
Zara, LF ;
Suarez, PAZ .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 227 (1-2) :263-267
[2]   Production of diesel-like fuel and other value-added chemicals from pyrolysis of animal fat [J].
Adebanjo, AO ;
Dalai, AK ;
Bakhshi, NN .
ENERGY & FUELS, 2005, 19 (04) :1735-1741
[3]   PYROLYSIS OF TROPICAL VEGETABLE-OILS [J].
ALENCAR, JW ;
ALVES, PB ;
CRAVEIRO, AA .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1983, 31 (06) :1268-1270
[4]   Current and potential uses of thermally treated olive oil waste [J].
Arvanitoyannis, Ioannis S. ;
Kassaveti, Aikaterini ;
Stefanatos, Stelios .
INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 2007, 42 (07) :852-867
[5]   Fatty acid methyl esters preparation in the presence of maltolate and n-butoxide Ti(IV) and Zr(IV) complexes [J].
Brito, Yariadner Costa ;
Mello, Vinicius Moreira ;
Macedo, Caio Cesar S. ;
Meneghetti, Mario Roberto ;
Suarez, Paulo A. Z. ;
Meneghetti, Simoni M. P. .
APPLIED CATALYSIS A-GENERAL, 2008, 351 (01) :24-28
[6]   CHINAS MOTOR FUELS FROM TUNG OIL [J].
CHANG, CC ;
WAN, SW .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1947, 39 (12) :1543-1548
[7]   Biodiesel production from crude palm oil and evaluation of butanol extraction and fuel properties [J].
Crabbe, E ;
Nolasco-Hipolito, C ;
Kobayashi, G ;
Sonomoto, K ;
Ishizaki, A .
PROCESS BIOCHEMISTRY, 2001, 37 (01) :65-71
[8]   Sustainable green diesel: A futuristic view [J].
Demirbas, A. ;
Dincer, K. .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2008, 30 (13) :1233-1241
[9]   Synthesis of biodiesel via homogeneous Lewis acid catalyst [J].
Di Serio, M ;
Tesser, R ;
Dimiccoli, M ;
Cammarota, F ;
Nastasi, M ;
Santacesaria, E .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 239 (1-2) :111-115
[10]   Comparing biofuels obtained from pyrolysis, of soybean oil or soapstock, with traditional soybean biodiesel: Density, kinematic viscosity, and surface tensions [J].
Doll, Kenneth A. ;
Sharma, Brajendra K. ;
Suarez, Paulo A. Z. ;
Erhan, Sevim Z. .
ENERGY & FUELS, 2008, 22 (03) :2061-2066