An Olefination via Ruthenium-Catalyzed Decarbonylative Addition of Aldehydes to Terminal Alkynes

被引：128
|
作者：
Guo, Xiangyu [1 ]
Wang, Jun [1 ]
Li, Chao-Jun [1 ]
机构：
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 42期
基金：
加拿大自然科学与工程研究理事会;
关键词：
WADSWORTH-EMMONS OLEFINATION; ATOM ECONOMY;
D O I：
10.1021/ja906265a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ruthenium-catatyzed olefination via decarbonylative addition of aldehydes; and alkynes has been developed. A strong electronic effect and high chemoselectivity between aromatic and aliphatic aldehydes were observed in this reaction.
引用
收藏
页码：15092 / +
页数：4
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