An improved set of electron-THFA cross sections refined through a neural network-based analysis of swarm data

被引:11
作者
Stokes, P. W. [1 ]
Foster, S. P. [1 ]
Casey, M. J. E. [1 ]
Cocks, D. G. [2 ]
Gonzalez-Magana, O. [3 ]
de Urquijo, J. [3 ]
Garcia, G. [4 ]
Brunger, M. J. [5 ,6 ]
White, R. D. [1 ]
机构
[1] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4811, Australia
[2] Australian Natl Univ, Res Sch Phys, Canberra, ACT 0200, Australia
[3] Univ Nacl Autonoma Mexico, Inst Ciencias Fis, Cuernavaca 62251, Morelos, Mexico
[4] CSIC, Inst Fis Fundamental, Serrano 113 Bis, Madrid 28006, Spain
[5] Flinders Univ S Australia, Coll Sci & Engn, Bedford Pk, Adelaide, SA 5042, Australia
[6] UCSI Univ, Fac Business & Management, Dept Actuarial Sci & Appl Stat, Kuala Lumpur 56000, Malaysia
基金
澳大利亚研究理事会;
关键词
ALPHA-TETRAHYDROFURFURYL ALCOHOL; MOMENTUM-TRANSFER; VIBRATIONAL-EXCITATION; BOLTZMANN-EQUATION; SCATTERING; TRANSPORT; DNA; CONSTITUENTS; COEFFICIENTS; IONIZATION;
D O I
10.1063/5.0043759
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We review experimental and theoretical cross sections for electron transport in alpha -tetrahydrofurfuryl alcohol (THFA) and, in doing so, propose a plausible complete set. To assess the accuracy and self-consistency of our proposed set, we use the pulsed-Townsend technique to measure drift velocities, longitudinal diffusion coefficients, and effective Townsend first ionization coefficients for electron swarms in admixtures of THFA in argon, across a range of density-reduced electric fields from 1 to 450 Td. These measurements are then compared to simulated values derived from our proposed set using a multi-term solution of Boltzmann's equation. We observe discrepancies between the simulation and experiment, which we attempt to address by employing a neural network model that is trained to solve the inverse swarm problem of unfolding the cross sections underpinning our experimental swarm measurements. What results from our neural network-based analysis is a refined set of electron-THFA cross sections, which we confirm is of higher consistency with our swarm measurements than that which we initially proposed. We also use our database to calculate electron transport coefficients in pure THFA across a range of reduced electric fields from 0.001 to 10 000 Td.
引用
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页数:18
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