Organic chemistry of siloxane and silanol

被引：8

作者：

Hirabayashi, K ^{[1
]}

Mori, A ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2000年 / 58卷 / 10期

关键词：

silicone; siloxane; silanol; cyclic siloxane; chiral silanol; neighboring effect; C-Si bond transformation;

D O I：

10.5059/yukigoseikyokaishi.58.926

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This article reviews organic chemistry of siloxane and silanol involving the preparative method as well as applications towards organic synthesis. Chapter 1 deals with the formation of siloxane bond and reactions of thus prepared siloxane compounds. Chapter 2 covers recent preparative methods for silanols and new synthetic reaction using silanol involving I) utilization of silanol oxygen that serves as a base or a nucleophile, 2) transformation of neighboring functionality on the silicon substituent based on the interaction of silanol oxygen with an organometallic reagent, and 3) transformation of a carbon silicon bond of silanols directed to novel carbon-carbon bond forming reactions.

引用

页码：926 / 933

页数：8

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