Eco-friendly approach for efficient catalytic degradation of organic dyes through peroxymonosulfate activated with pistachio shell-derived biochar and activated carbon

被引:14
|
作者
Gholami, Ali [1 ]
Mousavinia, Fakhreddin [1 ]
机构
[1] Univ Kashan, Fac Chem, Dept Analyt Chem, Kasha 8731753153, Iran
关键词
Pistachio shell; degradation; methylene blue; methyl orange; peroxymonosulfate; METHYLENE-BLUE; WASTE-WATER; AQUEOUS-SOLUTION; PHOTOCATALYTIC DEGRADATION; AZO-DYE; ORANGE; OXIDATION; ADSORPTION; PERSULFATE; REMOVAL;
D O I
10.1080/09593330.2021.1922510
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study introduces a simple method for the preparation of biochar (BCP) and activated carbon using pistachio (ACP) external hull as residual solid waste. Low-cost raw materials, biodegradable, recyclable and organic solid wastes are advantages of this method. Furthermore, complete degradation of methyl orange (MO) and methylene blue (MB) to H2O and CO2 as eco-friendly compounds in mild reaction condition occurs at a short time. Also, the effects of crucial parameters (temperature, time, catalyst dosage, initial dye and oxidant concentration, initial reaction pH level and radical scavengers), capability, adaptability, performance and reusability of ACP were also evaluated. The results displayed that dyes could be decomposed effectively by the PMS/ACP-800 system. Furthermore, the sulphate radical (SO4 center dot-) was a major active role in the degradation process, while hydroxyl radical ((OH)-O-center dot) played a minor role. Overall, ACP had yielded high degradation of MB and MO dyes; therefore, ACP-800 could be effectively and reliably applied in the treatment of industry effluents containing MB and MO dyes. [GRAPHICS] .
引用
收藏
页码:3444 / 3461
页数:18
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