Synthesis of a key reactive unit for use in the divergent or convergent synthesis of carbosilane dendrimers

被引：21

作者：

Gossage, RA ^{[1
]}

Munoz-Martinez, E ^{[1
]}

van Koten, G ^{[1
]}

机构：

[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 16期

关键词：

D O I：

10.1016/S0040-4039(98)00208-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new organosilane 4-triallylsilylphenol (1) can be synthesised in high yield via two routes using either 4-bromophenol or its silyl-group protected derivative as starting materials. Compound 1 can be used in the divergent or convergent synthesis of carbosilane dendrimers or conversely as a readily functionalisable dendrimer core unit. An improved synthesis of chlorotriallylsilane is also presented. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2397 / 2400

页数：4

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