Synthesis of a key reactive unit for use in the divergent or convergent synthesis of carbosilane dendrimers

被引：21
|
作者：
Gossage, RA [1 ]
Munoz-Martinez, E [1 ]
van Koten, G [1 ]
机构：
[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 16期
关键词：
D O I：
10.1016/S0040-4039(98)00208-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The new organosilane 4-triallylsilylphenol (1) can be synthesised in high yield via two routes using either 4-bromophenol or its silyl-group protected derivative as starting materials. Compound 1 can be used in the divergent or convergent synthesis of carbosilane dendrimers or conversely as a readily functionalisable dendrimer core unit. An improved synthesis of chlorotriallylsilane is also presented. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2397 / 2400
页数：4
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