Synthesis of a key reactive unit for use in the divergent or convergent synthesis of carbosilane dendrimers

被引：21

作者：

Gossage, RA ^{[1
]}

Munoz-Martinez, E ^{[1
]}

van Koten, G ^{[1
]}

机构：

[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 16期

关键词：

D O I：

10.1016/S0040-4039(98)00208-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new organosilane 4-triallylsilylphenol (1) can be synthesised in high yield via two routes using either 4-bromophenol or its silyl-group protected derivative as starting materials. Compound 1 can be used in the divergent or convergent synthesis of carbosilane dendrimers or conversely as a readily functionalisable dendrimer core unit. An improved synthesis of chlorotriallylsilane is also presented. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2397 / 2400

页数：4

共 50 条

[21] Synthesis of network polymers based on functional carbosilane dendrimers
Bystrova, AV
Tatarinova, EA
Buzin, MI
Muzafarov, AM
POLYMER SCIENCE SERIES A, 2005, 47 (08) : 820 - 827
[22] Synthesis, structure and molecular modelling of anionic carbosilane dendrimers
Rasines, Beatriz
Sanchez-Nieves, Javier
Maiolo, Massimo
Maly, Marek
Chonco, Louis
Luis Jimenez, Jose
Angeles Munoz-Fernandez, M.
Javier de la Mata, F.
Gomez, Rafael
DALTON TRANSACTIONS, 2012, 41 (41) : 12733 - 12748
[23] Synthesis of transition metal-containing carbosilane dendrimers
Rossell, O
Seco, M
Angurell, I
COMPTES RENDUS CHIMIE, 2003, 6 (8-10) : 803 - 817
[24] Synthesis of network polymers based on functional carbosilane dendrimers
Bystrova, A.V.
Tatarinova, E.A.
Buzin, M.I.
Muzafarov, A.M.
Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 2005, 47 (08): : 1459 - 1460
[25] Carbosilane dendrimers and monodendrons: Strategies for modular synthesis.
Stobart, SR
Berg, DJ
Casado, MA
Feng, SY
Hernandez-Gruel, MAF
Roovers, J
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U371 - U371
[26] Synthesis of carbosilane dendrimers based on tetrakis(phenylethynyl)silane
Kim, C
Kim, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 563 (1-2) : 43 - 51
[27] Divergent Synthesis of Porous Tetraphenylmethane Dendrimers
Urzua, Julio I.
Torneiro, Mercedes
JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (24): : 13231 - 13238
[28] Synthesis of Polyaryl Rigid-Core Carbosilane Dendrimers for Supported Organic Synthesis
Wander, Maaike
Hausoul, Peter J. C.
Sliedregt, Leo A. J. M.
van Steen, Bart J.
van Koten, Gerard
Gebbink, Robertus J. M. Klein
ORGANOMETALLICS, 2009, 28 (15) : 4406 - 4415
[29] Convergent Synthesis of Fluoroalkenes Using a Dual-Reactive Unit
Isoda, Motoyuki
Uetake, Yuta
Takimoto, Tadashi
Tsuda, Junpei
Hosoya, Takamitsu
Niwa, Takashi
JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (02): : 1622 - 1632
[30] The use of 1,2,3-thiadiazoles in the convergent synthesis of dendrimers
Labbe, G
Haelterman, B
Dehaen, W
BULLETIN DES SOCIETES CHIMIQUES BELGES, 1996, 105 (07): : 419 - 420

← 1 2 3 4 5 →