Thermally Driven Transport and Relaxation Switching Self-Powered Electromagnetic Energy Conversion

被引:892
作者
Cao, Maosheng [1 ]
Wang, Xixi [1 ]
Cao, Wenqiang [1 ]
Fang, Xiaoyong [2 ]
Wen, Bo [3 ]
Yuan, Jie [4 ]
机构
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[2] Yanshan Univ, Sch Sci, Qinhuangdao 066004, Peoples R China
[3] Australian Natl Univ, Coll Engn & Comp Sci, Res Sch Engn, Canberra, ACT 2601, Australia
[4] Minzu Univ China, Sch Sci, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
charge transport; electromagnetic energy conversion; graphene; relaxation; self-power; MICROWAVE-ABSORPTION ENHANCEMENT; ATOMIC LAYER DEPOSITION; TRIBOELECTRIC NANOGENERATOR; ELECTRICAL-CONDUCTIVITY; SHIELDING EFFECTIVENESS; CARBON NANOTUBES; FOAM COMPOSITES; GRAPHENE OXIDE; NANOCOMPOSITES; LIGHTWEIGHT;
D O I
10.1002/smll.201800987
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electromagnetic energy radiation is becoming a "health-killer" of living bodies, especially around industrial transformer substation and electricity pylon. Harvesting, converting, and storing waste energy for recycling are considered the ideal ways to control electromagnetic radiation. However, heat-generation and temperature-rising with performance degradation remain big problems. Herein, graphene-silica xerogel is dissected hierarchically from functions to "genes," thermally driven relaxation and charge transport, experimentally and theoretically, demonstrating a competitive synergy on energy conversion. A generic approach of "material genes sequencing" is proposed, tactfully transforming the negative effects of heat energy to superiority for switching self-powered and self-circulated electromagnetic devices, beneficial for waste energy harvesting, conversion, and storage. Graphene networks with "well-sequencing genes" (w = P-c/P-p > 0.2) can serve as nanogenerators, thermally promoting electromagnetic wave absorption by 250%, with broadened bandwidth covering the whole investigated frequency. This finding of nonionic energy conversion opens up an unexpected horizon for converting, storing, and reusing waste electromagnetic energy, providing the most promising way for governing electromagnetic pollution with self-powered and self-circulated electromagnetic devices.
引用
收藏
页数:8
相关论文
共 84 条
[1]   EMI shielding effectiveness of carbon based nanostructured polymeric materials: A comparative study [J].
Al-Saleh, Mohammed H. ;
Saadeh, Walaa H. ;
Sundararaj, Uttandaraman .
CARBON, 2013, 60 :146-156
[2]   Effect of synthesis catalyst on structure of nitrogen-doped carbon nanotubes and electrical conductivity and electromagnetic interference shielding of their polymeric nanocomposites [J].
Arjmand, Mohammad ;
Chizari, Kambiz ;
Krause, Beate ;
Poetschke, Petra ;
Sundararaj, Uttandaraman .
CARBON, 2016, 98 :358-372
[3]   Transport conductivity of graphene at RF and microwave frequencies [J].
Awan, S. A. ;
Lombardo, A. ;
Colli, A. ;
Privitera, G. ;
Kulmala, T. S. ;
Kivioja, J. M. ;
Koshino, M. ;
Ferrari, A. C. .
2D MATERIALS, 2016, 3 (01)
[4]   The effect of oxygen functional groups on the electrical transport behavior of a single piece multi-layered graphene oxide [J].
Baek, Seung Jae ;
Hong, Won G. ;
Park, Min ;
Kaiser, Alan B. ;
Kim, Hae Jin ;
Kim, Byung Hoon ;
Park, Yung Woo .
SYNTHETIC METALS, 2014, 191 :1-5
[5]  
Balci O., 2015, Nature Communications, V6
[6]   The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites [J].
Cao, Mao-Sheng ;
Song, Wei-Li ;
Hou, Zhi-Ling ;
Wen, Bo ;
Yuan, Jie .
CARBON, 2010, 48 (03) :788-796
[7]   Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes [J].
Che, RC ;
Peng, LM ;
Duan, XF ;
Chen, Q ;
Liang, XL .
ADVANCED MATERIALS, 2004, 16 (05) :401-+
[8]   High-Performance Epoxy Nanocomposites Reinforced with Three-Dimensional Carbon Nanotube Sponge for Electromagnetic Interference Shielding [J].
Chen, Yu ;
Zhang, Hao-Bin ;
Yang, Yanbing ;
Wang, Mu ;
Cao, Anyuan ;
Yu, Zhong-Zhen .
ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (03) :447-455
[9]   Lightweight and Flexible Graphene Foam Composites for High-Performance Electromagnetic Interference Shielding [J].
Chen, Zongping ;
Xu, Chuan ;
Ma, Chaoqun ;
Ren, Wencai ;
Cheng, Hui-Ming .
ADVANCED MATERIALS, 2013, 25 (09) :1296-1300
[10]  
Chen ZP, 2011, NAT MATER, V10, P424, DOI [10.1038/nmat3001, 10.1038/NMAT3001]