Synthesis, spectroscopic and crystallographic characterization of the cobalt(III) ternary mixed-ligand complexes of N(4)-allyl/methyl thiosemicarbazones, N,N,N',N'-tetramethylethylenediamine and azide

被引：11

作者：

Bal-Demirci, Tuelay ^{[1
]}

Akkurt, Mehmet ^{[2
]}

Yalcin, Serife Pinar ^{[2
]}

Buyukgungor, Orhan ^{[3
]}

机构：

[1] Istanbul Univ, Dept Chem, TR-34320 Istanbul, Turkey

[2] Erciyes Univ, Dept Phys, Fac Arts & Sci, TR-38039 Kayseri, Turkey

[3] Ondokuz Mayis Univ, Dept Phys, Fac Arts & Sci, TR-55139 Samsun, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2010年 / 35卷 / 01期

关键词：

CRYSTAL-STRUCTURE; COPPER(II) COMPLEXES; NICKEL(II) COMPLEXES; DNA-BINDING; ANTIBACTERIAL; NONLINEARITY; NI;

D O I：

10.1007/s11243-009-9300-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed-ligand ternary cobalt(III) complexes consisting of N,N,N',N'-tetramethylethylenediamine (tmen), R-salicylaldehyde-N(4)-allyl/methyl thiosemicarbazones (R=3-OMe (L-I/L-II) or H (L-III/L-IV) and azide, of general formula [CoL(tmen)(N-3)], were synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structure of [CoLI(tmen)(N-3)] has a slightly distorted octahedral coordination geometry involving the O, N and S atoms of thiosemicarbazone.

引用

页码：95 / 102

页数：8

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