Cationic Metallogermylene and Dicationic Dimetallodigermenes: Synthesis by Chloride Abstraction from N-Heterocyclic Carbene-Stabilized Chlorometallogermylenes ocr issue

被引：51

作者：

Inomata, Koya ^{[1
]}

Watanabe, Takahito ^{[1
]}

Tobita, Hiromi ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 41期

关键词：

MAIN-GROUP ELEMENTS; GERMANIUM(II); COMPLEXES; CONVERSION; SILICON; BONDS; TIN; SN;

D O I：

10.1021/ja506018f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr4 (Ar = 3,5-(CF3)(2)C6H3) gave a cationic metallogermylene or dicationic dimetallodigermenes.

引用

页码：14341 / 14344

页数：4

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