Adsorption efficiency of date palm based activated carbon-alginate membrane for methylene blue

被引:78
作者
Durrani, Wishal Zia [1 ]
Nasrullah, Asma [1 ]
Khan, Amir Sada [1 ]
Fagieh, Taghreed M. [2 ]
Bakhsh, Esraa M. [2 ]
Akhtar, Kalsoom [2 ]
Khan, Sher Bahadar [2 ,3 ]
Din, Israf Ud [4 ]
Khan, Muhammad Azam [5 ]
Bokhari, Awais [6 ,7 ]
机构
[1] Univ Sci & Technol, Dept Chem, Bannu 28100, Khyber Pakhtunk, Pakistan
[2] King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
[3] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, POB 80203, Jeddah 21589, Saudi Arabia
[4] Prince Sattam Bin Abdulaziz Univ, Coll Sci & Humanities, Dept Chem, POB 173, Al Kharj, Saudi Arabia
[5] Pir Mehr Ali Shah Arid Agr Univ, Dept Hort, Rawalpindi 46300, Pakistan
[6] COMSATS Univ Islamabad CUI, Dept Chem Engn, Lahore Campus,Def Rd Off Rawind Rd, Lahore 54000, Punjab, Pakistan
[7] Brno Univ Technol VUT Brno, Fac Mech Engn, NETME Ctr, Sustainable Proc Integrat Lab, Tech 2896-2, Brno 61669, Czech Republic
关键词
Activated carbon; Composite membrane; Adsorption; Isotherm study; Thermodynamic study; AQUEOUS-SOLUTION; PROCESS OPTIMIZATION; CR(VI) ADSORPTION; NAOH ACTIVATION; REMOVAL; DYE; KINETICS; THERMODYNAMICS; EQUILIBRIUM; WASTE;
D O I
10.1016/j.chemosphere.2022.134793
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the current study, activated carbon (AC) was prepared from date palm using single step activation using boric acid as an activating agent. The synthesized AC was incorporated with alginate (AC-alginate (AC-alg)) to prepare membrane for adsorption of methylene blue (MB) in batch adsorption study. The prepared membrane was characterized using different types of analytical techniques such as FTIR, SEM, and TGA analysis. Adsorption of methylene blue dye from aqueous solution was carried out using AC-alg membrane in batch investigation. Various experimental parameters effecting the adsorption of MB on membrane such as initial pH of dye solution, contact time, concentration of dye solution and temperature were optimized to get maximum adsorption efficiency. Kinetics, isotherm and thermodynamics study was performed for dye adsorption. Pseudo-second order kinetic model and Langmuir adsorption isotherm were well fitted to the experimental data. The maximum adsorption capacity for MB adsorption was 666 mg/g found by Langmuir adsorption isotherm. Thermodynamic study revealed that the adsorption of MB on AC-alg membrane is spontaneous and an exothermic process. The
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页数:9
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共 52 条
  • [1] Development of activated carbon from Phoenix dactylifera fruit pits: process optimization, characterization, and methylene blue adsorption
    Aldawsari, Abdullah
    Khan, Moonis Ali
    Hameed, B. H.
    AlOthman, Zeid Abdullah
    Siddiqui, Masoom Raza
    Ahmed, A. Yacine Badjah Hadj
    Alsohaimi, Ibrahim Hotan
    [J]. DESALINATION AND WATER TREATMENT, 2017, 62 : 273 - 281
  • [2] Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin
    Alnarabiji, Mohamad Sahban
    Yahya, Noorhana
    Hamed, Yaman
    Ardakani, Seyed Esmaeil Mandavi
    Azizi, Khairun
    Klemes, Jiri Jaromir
    Abdullah, Bawadi
    Tasfy, Sara Faiz Hanna
    Abd Hamid, Sharifa Bee
    Nashed, Omar
    [J]. JOURNAL OF CLEANER PRODUCTION, 2017, 162 : 186 - 194
  • [3] Water pollution in Pakistan and its impact on public health - A review
    Azizullah, Azizullah
    Khattak, Muhammad Nasir Khan
    Richter, Peter
    Hader, Donat-Peter
    [J]. ENVIRONMENT INTERNATIONAL, 2011, 37 (02) : 479 - 497
  • [4] Adsorption of acid dye onto organobentonite
    Baskaralingam, P
    Pulikesi, M
    Elango, D
    Ramamurthi, V
    Sivanesan, S
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2006, 128 (2-3) : 138 - 144
  • [5] REMOVAL OF HEAVY-METALS FROM WATERS BY MEANS OF NATURAL ZEOLITES
    BLANCHARD, G
    MAUNAYE, M
    MARTIN, G
    [J]. WATER RESEARCH, 1984, 18 (12) : 1501 - 1507
  • [6] Application of Response Surface Methodology for Methylene Blue dye removal from aqueous solution using low cost adsorbent
    Chatterjee, Soumasree
    Kumar, Atul
    Basu, Srabanti
    Dutta, Susmita
    [J]. CHEMICAL ENGINEERING JOURNAL, 2012, 181 : 289 - 299
  • [7] Adsorption of methylene blue onto poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) nanotubes: Kinetics, isotherm and thermodynamics analysis
    Chen, Zhonghui
    Zhang, Jianan
    Fu, Jianwei
    Wang, Minghuan
    Wang, Xuzhe
    Han, Runping
    Xu, Qun
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2014, 273 : 263 - 271
  • [8] Christie RM, 2007, WOODHEAD PUBL SER TE, P1
  • [9] Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics, mechanism and process design
    Dawood, Sara
    Sen, Tushar Kanti
    [J]. WATER RESEARCH, 2012, 46 (06) : 1933 - 1946
  • [10] Adsorbents for industrial pollution control
    El-Geundi, MS
    [J]. ADSORPTION SCIENCE & TECHNOLOGY, 1997, 15 (10) : 777 - 787