Synthesis and crystal structures of P-halogeno(imino)methylenephosphoranes X-P(=NtBu3C6H2)=C(SiMe3)2 (X=Cl, Br, I)

被引：0

作者：

Ruban, A ^{[1
]}

Nieger, M ^{[1
]}

Niecke, E ^{[1
]}

机构：

[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 1998年 / 01期

关键词：

phosphorus ylides; bis(ylene)phosphoranes; halogenophosphoranes; X-ray structure analysis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iminophosphane (Me3Si)(3)C-P=N-Mes* (1) reacts with iodine to form the imino(methylene)phosphorane I-P(=N-Mes*)=C(SiMe3)(2) (2). Upon subsequent treatment with AgCl, the corresponding chloro derivative 3 is obtained.

引用

页码：83 / 85

页数：3

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