Silicon-carbon bond cleavage of organosilicon amines MenN[CH2Si(OCH2CH2)3N]3-n (n=1, 2) by phenols

被引：16

作者：

Lazareva, NF ^{[1
]}

Brodskaya, EI ^{[1
]}

Ratovsky, GV ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Inst Chem, Irkutsk 664033, Russia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2002年 / 12期

关键词：

D O I：

10.1039/b207208d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anomalously high basicity of organosilicon amines MenN[CH2Si(OCH2CH2)(3)N](3-n) determines the ease of nucleophilic cleavage of the Si-C bond by phenols even at room temperature. The conversion of silatrane increases both with phenol acidity and basicity of the exocyclic nitrogen atom.

引用

页码：2083 / 2086

页数：4

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