Photocatalytie Activity of Porous Magnesium Oxychloride Cement Combined with AC/TiO2 Composites

被引:10
作者
Feng Chuanfa [1 ]
Wang Fazhou [1 ]
Liu Peng [1 ,2 ]
Sun Guoxin [1 ]
Yang Lu [1 ]
Zhang Wenqin [1 ]
Shu Chang [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
[2] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
photocatalysis; cementitious material; adsorbent enhancement; TiO2; photocatalyst; toluene degradation; ACTIVATED CARBON; PHOTODEGRADATION BEHAVIORS; TIO2; PERFORMANCE; NANOMATERIALS; AIR;
D O I
10.1007/s11595-017-1639-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
As a decorative material, magnesium oxychloride cement was used as a photocatalyst supporter to purify the pollutants indoors. Due to excellent adsorption properties of activated carbon (AC), the photocatalvtic composties. TiO2/AC, were prepared and introduced into the porous magnesium oxychloride cement (PMOC) substrate to composite a sort of photocatalytic cementitious material (PCM). The optimal composite processes were assessed by gas chromatograph, using toluene as the target. By comparing the perspective of toluene purification and thorough decomposition, it can be found that the optimal mass ratio for TiO2/AC composites is 4/25, and the heat treatment to TiO2/AC sample at 350 degrees C can play the optimal synergetic role of adsorbents in photocatalytic process. The synergistic effect of TiO2 AC and magnesium oxychloride cement (MOC) was also evaluated by gas chromatograph. One-take molding process was adopted to introduce the TiO2/AC into PMOC substrate, and its optimal mass fraction was 4 wt%, while the appropriate density of substrate was 0.35 g/cm(3). Toluene degradation showed that the prepared PCM can degrade pollutants efficiently. The appropriate treatment process of TiO2/AC, mass of TiO2/AC, substrate density, and stable pore structure should be coordinated to maximize the adsorption-photodegradation performance. The combination of photocatalytic materials, adsorbents, and building materials provided a new idea for the application of photocatalysis.
引用
收藏
页码:591 / 597
页数:7
相关论文
共 25 条
[1]   Characterization and photocatalytic performance in air of cementitious materials containing TiO2. Case study of formaldehyde removal [J].
Aissa, Aurelie Hadj ;
Puzenat, Eric ;
Plassais, Arnaud ;
Herrmann, Jean-Marie ;
Haehnel, Claude ;
Guillard, Chantal .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 107 (1-2) :1-8
[2]   Photoinduced reactivity of titanium dioxide [J].
Carp, O ;
Huisman, CL ;
Reller, A .
PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) :33-177
[3]   Microstructures of magnesium oxychloride [J].
Chau, C. K. ;
Li, Zongjin .
MATERIALS AND STRUCTURES, 2008, 41 (05) :853-862
[4]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[5]  
Korosi L, 2012, CATALYSIS ALTERNATIV
[6]   Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis [J].
Leary, Rowan ;
Westwood, Aidan .
CARBON, 2011, 49 (03) :741-772
[7]   Photocatalytic purification of volatile organic compounds in indoor air: A literature review [J].
Mo, Jinhan ;
Zhang, Yinping ;
Xu, Qiujian ;
Lamson, Jennifer Joaquin ;
Zhao, Rongyi .
ATMOSPHERIC ENVIRONMENT, 2009, 43 (14) :2229-2246
[8]   Application of TiO2 photocatalysis for air treatment: Patents' overview [J].
Paz, Yaron .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 99 (3-4) :448-460
[9]   Photocatalytic activity of TiO2-SiO2 nanocomposites applied to buildings: Influence of particle size and loading [J].
Pinho, Luis ;
Mosquera, Maria J. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 134 :205-221
[10]   Semiconductor Photocatalysis - Past, Present, and Future Outlook [J].
Serpone, N. ;
Emeline, A. V. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (05) :673-677