Intermolecular hydrogen•••metal interactions.: The crystal structure of {cis-[PdCl2(TPA)2]}2•H2O, a water-soluble palladium(II) tertiary phosphine complex

被引：35

作者：

Alyea, EC ^{[1
]}

Ferguson, G ^{[1
]}

Kannan, S ^{[1
]}

机构：

[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a706243e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The single-crystal X-ray structural determination of {cis-[PdCl2(TPA)(2)]}(2) . H2O (TPA = 1,3,5-triaza-7-phosphaadamantane) establishes that pairs of cis-[PdCl2(TPA)(2)] molecules are linked about inversion centres by intermolecular Pd ... H ... C three-centre-four-electron interactions (2.86, 3.00 Angstrom for the two independent dimers); the water molecule links these dimers via O-H ... N hydrogen bonds to form infinite chains extending in the c-direction in the crystal lattice.

引用

页码：345 / 346

页数：2

共 34 条

[1] WEAK PT-H-C INTERACTIONS - EXTENSIONS TO 8-METHYLQUINOLINE, BENZOQUINOLINE, AND A TETRALONE SCHIFF-BASE - X-RAY CRYSTAL-STRUCTURE OF TRANS-PTCL2(BENZOQUINOLINE)(PET3) [J].

ALBINATI, A ;

PREGOSIN, PS ;

WOMBACHER, F .

INORGANIC CHEMISTRY, 1990, 29 (10) :1812-1817

[2] CIS-DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) [J].

ALCOCK, NW ;

NELSON, JH .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 :1748-1750

[3] PHOTOCHEMICAL PREPARATION OF THE CIS ISOMERS OF DICHLOROBIS(TRI-N-ALKYLPHOSPHINE)PALLADIUM(II) (ALKYL = ET, PRN, OR BUN) - THE CRYSTAL-STRUCTURE ANALYSIS OF THE OVERCROWDED N-PROPYL HOMOLOG [J].

ALCOCK, NW ;

KEMP, TJ ;

WIMMER, FL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (02) :635-638

[4] SYNTHESIS, SOLID-STATE P-31 CP-MAS NMR INFRARED AND RAMAN STUDIES OF MERCURY(II) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (PTA) [J].

ALYEA, EC ;

FISHER, KJ ;

JOHNSON, S .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (08) :1319-1323

[5] A P-31 AND MO-95 NMR-STUDY OF SOME MOLYBDENUM AND TUNGSTEN CARBONYL-COMPLEXES OF A SMALL AIR-STABLE ALIPHATIC PHOSPHINE, 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (PTA) [J].

ALYEA, EC ;

FISHER, KJ ;

FOO, S ;

PHILIP, B .

POLYHEDRON, 1993, 12 (05) :489-492

[6]

ALYEA EC, 1988, 3 CHEM C N AM JUN 5

[7]

ALYEA EC, 1997, IN PRESS POLYHEDRON, V16

[8]

ALYEA EC, 1998, IN PRESS POLYHEDRON, V17

[9] SYNTHESES, STRUCTURES, AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) - CORRELATION OF THE SUPRAMOLECULAR AU...AU INTERACTION AND PHOTOLUMINESCENCE FOR THE SPECIES (TPA)AUCL AND [(TPA-HCL)AUCL] [J].

ASSEFA, Z ;

MCBURNETT, BG ;

STAPLES, RJ ;

FACKLER, JP ;

ASSMANN, B ;

ANGERMAIER, K ;

SCHMIDBAUR, H .

INORGANIC CHEMISTRY, 1995, 34 (01) :75-83

[10] THE ROLE OF TRANSITION-METAL ATOMS AS HYDROGEN-BOND ACCEPTORS - A NEUTRON-DIFFRACTION STUDY OF [NPRN4]2[PTCL4].CIS-[PTCL2(NH2ME)2] AT 20-K [J].

BRAMMER, L ;

CHARNOCK, JM ;

GOGGIN, PL ;

GOODFELLOW, RJ ;

ORPEN, AG ;

KOETZLE, TF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07) :1789-1798

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