Enhanced saturation lithium composition in ball-milled single-walled carbon nanotubes

被引：268

作者：

Gao, B ^{[1
]}

Bower, C ^{[1
]}

Lorentzen, JD ^{[1
]}

Fleming, L ^{[1
]}

Kleinhammes, A ^{[1
]}

Tang, XP ^{[1
]}

McNeil, LE ^{[1
]}

Wu, Y ^{[1
]}

Zhou, O ^{[1
]}

机构：

[1] Univ N Carolina, Dept Phys & Astron, Chapel Hill, NC 27599 USA

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 327卷 / 1-2期

基金：

美国国家航空航天局;

关键词：

D O I：

10.1016/S0009-2614(00)00851-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effects of processing on the structure and morphology of single-walled carbon nanotubes (SWNT) and their electrochemical intercalation with lithium were investigated. Purified SWNTs were processed by impact ball-milling and were electrochemically intercalated with lithium. The reversible saturation Li composition increased from Li1.7C6 in purified SWNTs to Li2.7C6 after 10 min of milling. The irreversible capacity decreased from Li3.2C6 to Li1.3C6. Electron microscopy, Raman and X-ray diffraction measurements indicated that ball-milling induced disorder within the bundles and fractured the nanotubes. (C) 2000 Published by Elsevier Science B.V.

引用

页码：69 / 75

页数：7

共 27 条

[11] Electrochemical intercalation of single-walled carbon nanotubes with lithium [J].

Gao, B ;

Kleinhammes, A ;

Tang, XP ;

Bower, C ;

Fleming, L ;

Wu, Y ;

Zhou, O .

CHEMICAL PHYSICS LETTERS, 1999, 307 (3-4) :153-157

[12] LI METAL-FREE RECHARGEABLE LIMN2O4/CARBON CELLS - THEIR UNDERSTANDING AND OPTIMIZATION [J].

GUYOMARD, D ;

TARASCON, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (04) :937-948

[13] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[14] Conductivity enhancement in single-walled carbon nanotube bundles doped with K and Br [J].

Lee, RS ;

Kim, HJ ;

Fischer, JE ;

Thess, A ;

Smalley, RE .

NATURE, 1997, 388 (6639) :255-257

[15]

PISTORIA G, 1994, LITHIUM BATTERIES NE

[16] Evidence for charge transfer in doped carbon nanotube bundles from Raman scattering [J].

Rao, AM ;

Eklund, PC ;

Bandow, S ;

Thess, A ;

Smalley, RE .

NATURE, 1997, 388 (6639) :257-259

[17] A MECHANISM OF LITHIUM STORAGE IN DISORDERED CARBONS [J].

SATO, K ;

NOGUCHI, M ;

DEMACHI, A ;

OKI, N ;

ENDO, M .

SCIENCE, 1994, 264 (5158) :556-558

[18] Purification of single-wall carbon nanotubes by ultrasonically assisted filtration [J].

Shelimov, KB ;

Esenaliev, RO ;

Rinzler, AG ;

Huffman, CB ;

Smalley, RE .

CHEMICAL PHYSICS LETTERS, 1998, 282 (5-6) :429-434

[19] Observation of potassium-intercalated carbon nanotubes and their valence-band excitation spectra [J].

Suzuki, S ;

Tomita, M .

JOURNAL OF APPLIED PHYSICS, 1996, 79 (07) :3739-3743

[20] In-situ TEM and EELS studies of alkali-metal intercalation with single-walled carbon nanotubes [J].

Suzuki, S ;

Bower, C ;

Zhou, O .

CHEMICAL PHYSICS LETTERS, 1998, 285 (3-4) :230-234

← 1 2 3 →