Catalytic Conversion of Levulinic Acid and Its Esters to γ-Valerolactone over Silica-Supported Zirconia Catalysts

被引：23

作者：

Kuwahara, Yasutaka ^{[1
,2
]}

Kaburagi, Wako ^{[1
]}

Fujitani, Tadahiro ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Inst Innovat Sustainable Chem, Tsukuba, Ibaraki 3058565, Japan

[2] Osaka Univ, Grad Sch Engn, Div Mat & Mfg Sci, Suita, Osaka 5650871, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2014年 / 87卷 / 11期

关键词：

MEERWEIN-PONNDORF-VERLEY; LIQUID-HYDROCARBON FUELS; PLATFORM MOLECULES; ETHYL LEVULINATE; BIOMASS; REDUCTION; HYDROGENATION; CHEMICALS; ZEOLITE; TRANSFORMATION;

D O I：

10.1246/bcsj.20140205

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Levulinic acid and its esters, important intermediate chemicals produced from biomass resources, were converted to gamma-valerolactone via a catalytic transfer hydrogenation process over silica-supported zirconia catalysts. Silica support with a higher surface area provided highly dispersed active zirconium oxide species, which exhibited superior catalytic activity to the conventional ZrO2 catalyst.

引用

页码：1252 / 1254

页数：3

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