Metal complexes of biologically important ligands.: XCV -: η5-pentamethylcyclopentadienyl rhodium, iridium, η6-benzene ruthenium, and phosphine palladium complexes of proline methylester and proline amide

被引：20

作者：

Hoffmuller, W ^{[1
]}

Polborn, K ^{[1
]}

Knizek, J ^{[1
]}

Noth, H ^{[1
]}

Beck, W ^{[1
]}

机构：

[1] Univ Munich, Inst Anorgan Chem, D-80333 Munich, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 12期

关键词：

rhodium; ruthenium; iridium; palladium; proline amide complexes; proline methylester complexes; crystal structure;

D O I：

10.1002/zaac.19976231214

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Proline methylester (L-1) and proline amide (L-2) give with the chloro bridged complexes [(eta(5)-C5Me5)MCl2](2) (M = Rh, Ir), [(eta(6)-benzene)RuCl2](2) and [Et3PPdCl2](2) N and N,O coordinated compounds: (eta(5)-C5Me5)M(Cl-2)L-1 (1, 2 M = Rh, Ir), [(eta(5)-C5Me5)Rh(Cl)(L-2)]Cl-+(-) (5), [(eta(6)-C6Me6)Ru(Cl)(L-2)]Cl-+(-) (6), [(eta(6)-p-cymene)Ru(Cl)(L-2)]Cl-+(-) (7), [(eta(5)-C5Me5)M(Cl)(L-2-H+)] (9, 10 M=Rh, Ir), (Et3P)Pd(Cl)(2)L-1 (3), and [(Et3P)Pd(Cl)(L-2)]Cl-+(-) (8). The NMR spectra indicate that for 5 and 6 only one diastereoisomer is formed. The complexes 1, 2, 3 and 5 were characterized by X-ray diffraction.

引用

页码：1903 / 1911

页数：9

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