Syntheses and crystal structure analyses of [SbI3(SbMe3)(THF)]2 and [Li(THF)4]2[Bi2Cl8(THF)2]

被引：0
|
作者：
Breunig, HJ [1 ]
Denker, M [1 ]
Schulz, RE [1 ]
Lork, E [1 ]
机构：
[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 01期
关键词：
antimony; bismuth; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199801)624:1<81::AID-ZAAC81>3.0.CO;2-K
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Me3Sb with SbI3 in tetrahydrofuran (THF) gives [SbI3(SbMe3)(THF)](2) (1). [Li(THF)(4)](2)[Bi2Cl8(THF)(2)] (2) is formed by reaction of LiCl and BiCl3 in tetrahydrofuran. The structures of (1) and (2) have been determined by X-ray diffractometry. Both structures contain centrosymmetric dimers with the geometry of edge sharing octahedra.
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页码：81 / 84
页数：4
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