Synthesis and activation potential of an open shell diphosphine

被引：15

作者：

Helmdach, Kai ^{[1
]}

Ludwig, Stephan ^{[1
]}

Villinger, Alexander ^{[1
]}

Hollmann, Dirk ^{[2
]}

Koesters, Jutta ^{[3
]}

Seidel, Wolfram W. ^{[1
]}

机构：

[1] Univ Rostock, Inst Chem, Albert Einstein Str 3a, D-18059 Rostock, Germany

[2] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

[3] Westfalische Wilhelms Univ Munster, Inst Anorgan & Analyt Chem, Corrensstr 30-36, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 43期

关键词：

O BOND-CLEAVAGE; REDOX-ACTIVE LIGANDS; NITRIC-OXIDE; STRUCTURAL CONSEQUENCES; CRYSTAL-STRUCTURE; ELECTRON-TRANSFER; ALKYNE COMPLEXES; METAL-COMPLEXES; CATALYSIS; NO;

D O I：

10.1039/c7cc02114c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A paramagneticW(III) alkyne complex bearing free terminal diphenylphosphino groups at the side-on coordinated alkyne was synthesized using a stepwise template strategy. This moderately stable metal supported open shell diphosphine shows an unprecedented spontaneous splitting of nitric oxide providing a W-II-eta(2)-C-2{P(NH2)Ph-2}{P(O)Ph-2}(+) complex featuring an amino phosphonium and a phosphine oxide substituent.

引用

页码：5894 / 5897

页数：4