Synthesis and activation potential of an open shell diphosphine

被引：15
作者：
Helmdach, Kai [1 ]
Ludwig, Stephan [1 ]
Villinger, Alexander [1 ]
Hollmann, Dirk [2 ]
Koesters, Jutta [3 ]
Seidel, Wolfram W. [1 ]
机构：
[1] Univ Rostock, Inst Chem, Albert Einstein Str 3a, D-18059 Rostock, Germany
[2] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
[3] Westfalische Wilhelms Univ Munster, Inst Anorgan & Analyt Chem, Corrensstr 30-36, D-48149 Munster, Germany
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 43期
关键词：
O BOND-CLEAVAGE; REDOX-ACTIVE LIGANDS; NITRIC-OXIDE; STRUCTURAL CONSEQUENCES; CRYSTAL-STRUCTURE; ELECTRON-TRANSFER; ALKYNE COMPLEXES; METAL-COMPLEXES; CATALYSIS; NO;
D O I：
10.1039/c7cc02114c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A paramagneticW(III) alkyne complex bearing free terminal diphenylphosphino groups at the side-on coordinated alkyne was synthesized using a stepwise template strategy. This moderately stable metal supported open shell diphosphine shows an unprecedented spontaneous splitting of nitric oxide providing a W-II-eta(2)-C-2{P(NH2)Ph-2}{P(O)Ph-2}(+) complex featuring an amino phosphonium and a phosphine oxide substituent.
引用
收藏
页码：5894 / 5897
页数：4
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