Synthesis and X-ray Crystal Structures of Ga-substituted Distibenes [L(X)GaSb]2

被引：23

作者：

Krueger, Julia ^{[1
,2
]}

Schoening, Juliane ^{[1
,2
]}

Ganesamoorthy, Chelladurai ^{[1
,2
]}

John, Lukas ^{[1
,2
]}

Woelper, Christoph ^{[1
,2
]}

Schulz, Stephan ^{[1
,2
]}

机构：

[1] Univ Duisburg Essen, Fac Chem, D-45117 Essen, Germany

[2] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen CENIDE, D-45117 Essen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2018年 / 644卷 / 17期

关键词：

Gallium; Antimony; Multiple bonds; X-ray diffraction; MAIN-GROUP ELEMENTS; DOUBLY BONDED SYSTEMS; MULTIPLE BONDS; CHEMISTRY SYNTHESIS; CARBENE ANALOG; DIPNICTENES; REACTIVITY; REDUCTION; SB; DIBISMUTHENE;

D O I：

10.1002/zaac.201800204

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of two equivalents of LGa {L = HC[C(Me)N(2,6-iPr(2)C(6)H(3))](2)} with SbX3 (X = Br, I, OEt) proceed with elimination of LGaX2 and formation of Ga-substituted distibenes [L(X)GaSb](2) [X = Br (1), I (2), OEt (3)]. Compounds 1 to 3 were characterized by heteronuclear NMR (H-1, C-13), IR and UV/Vis spectroscopy, elemental analysis, and single-crystal X-ray diffraction.

引用

页码：1028 / 1033

页数：6

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