Gibbs entropy and irreversible thermodynamics

被引:36
作者
Rondoni, L
Cohen, EGD
机构
[1] Politecn Torino, Dipartimento Matemat, I-10129 Turin, Italy
[2] Rockefeller Univ, New York, NY 10021 USA
关键词
D O I
10.1088/0951-7715/13/6/303
中图分类号
O29 [应用数学];
学科分类号
070104 ;
摘要
Recently, a number of approaches have been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in non-equilibrium stationary states, via the theory of dynamical systems. In this way a direct connection between dynamics and irreversible thermodynamics has been claimed to have been found. However, the main quantity used in these studies is a (coarse-grained) Gibbs entropy, which to us does not seem suitable, in its present form, to characterize non-equilibrium states. Various simplified models have also been devised to give explicit examples of how the coarse-grained approach may succeed in giving a full description of the irreversible thermodynamics. We analyse some of these models and point out a number of difficulties which, in our opinion, need to be overcome in order to establish a physically relevant connection between these models and irreversible thermodynamics. AMS classification scheme numbers: 82C05, 80A20, 70F25.
引用
收藏
页码:1905 / 1924
页数:20
相关论文
共 25 条
[1]   (Global and local) fluctuations of phase space contraction in deterministic stationary nonequilibrium [J].
Bonetto, F ;
Chernov, NI ;
Lebowitz, JL .
CHAOS, 1998, 8 (04) :823-833
[2]   Entropy balance, time reversibility, and mass transport in dynamical systems [J].
Breymann, W ;
Tel, T ;
Vollmer, J .
CHAOS, 1998, 8 (02) :396-408
[3]   Entropy production for open dynamical systems [J].
Breymann, WG ;
Tel, T ;
Vollmer, J .
PHYSICAL REVIEW LETTERS, 1996, 77 (14) :2945-2948
[4]   Note on phase space contraction and entropy production in thermostatted Hamiltonian systems [J].
Cohen, EGD ;
Rondoni, L .
CHAOS, 1998, 8 (02) :357-365
[5]  
Cornfeld I. P., 1982, Ergodic Theory
[6]  
De Groot S. R., 1984, NONEQUILIBRIUM THERM
[7]  
De Groot S.R., 1952, Thermodynamics of Irreversible Processes
[8]  
DETTMANN CP, 1996, PHYS REV E, V54, P4872
[9]  
Dorfman J. R., 1999, INTRO CHAOS NONEQUIL
[10]  
Evans D.J., 1990, STAT MECH NONEQUILIB