Synthesis and crystal structure of a new organic metal with honeycomb dithiooxalato-bridged anionic network, β"-(ET)2{[NMe3Ph]NaCr(C2S2O2)3(MeCN)}

被引：2

作者：

Zhilyaeva, EI ^{[1
]}

Shilov, GV

Bogdanova, OA

Lyubovskaya, RN

Lyubovskii, RB

Ovanesyan, NS

Aldoshin, SM

Train, C

Gruselle, M

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Noscow Region, Russia

[2] Univ Paris 06, Lab Chim Inorgan & Mat Mol, CNRS, U7071, F-75252 Paris, France

来源：

SYNTHETIC METALS | 2005年 / 148卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

organic conductors based on radical cation salts; electrical conductivity; X-ray diffraction;

D O I：

10.1016/j.synthmet.2004.09.035

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The first bis(ethylenedithio)tetrathiafulvalene (ET) based radical cation salt with a bimetallic dithiooxalato-bridged anionic network, beta"-(ET)(2){[NMe3Ph]NaCr(C2S2O2)(3)(MeCN)} has been prepared. The compound is metallic down to 60 K, at lower temperatures the resistance grows smoothly. The structure of beta"-(ET)(2){[NMe3Ph]NaCr(C2S2O2)(3)(MeCN)} has been determined from single-crystal X-ray diffraction and is characterized by alternation a conducting donor layer of the beta"-type packing with three insulating layers, two of which are {[NaCr(dto)(3)](2-)}(infinity) anionic networks and the third one, interleaving them, is formed by [NMe3Ph](+) organic cations and acetonitrile solvent molecules. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：251 / 255

页数：5

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