Synthesis and crystal structure of a new organic metal with honeycomb dithiooxalato-bridged anionic network, β"-(ET)2{[NMe3Ph]NaCr(C2S2O2)3(MeCN)}

被引：2
作者：
Zhilyaeva, EI [1 ]
Shilov, GV
Bogdanova, OA
Lyubovskaya, RN
Lyubovskii, RB
Ovanesyan, NS
Aldoshin, SM
Train, C
Gruselle, M
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Noscow Region, Russia
[2] Univ Paris 06, Lab Chim Inorgan & Mat Mol, CNRS, U7071, F-75252 Paris, France
来源：
SYNTHETIC METALS | 2005年 / 148卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
organic conductors based on radical cation salts; electrical conductivity; X-ray diffraction;
D O I：
10.1016/j.synthmet.2004.09.035
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The first bis(ethylenedithio)tetrathiafulvalene (ET) based radical cation salt with a bimetallic dithiooxalato-bridged anionic network, beta"-(ET)(2){[NMe3Ph]NaCr(C2S2O2)(3)(MeCN)} has been prepared. The compound is metallic down to 60 K, at lower temperatures the resistance grows smoothly. The structure of beta"-(ET)(2){[NMe3Ph]NaCr(C2S2O2)(3)(MeCN)} has been determined from single-crystal X-ray diffraction and is characterized by alternation a conducting donor layer of the beta"-type packing with three insulating layers, two of which are {[NaCr(dto)(3)](2-)}(infinity) anionic networks and the third one, interleaving them, is formed by [NMe3Ph](+) organic cations and acetonitrile solvent molecules. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：251 / 255
页数：5
相关论文
共 50 条
  • [1] A new organic metal with thedithiooxalato-bridged anion network, β"-ET)2{[NMe3Ph]NaCr(C2S2O2)3(MeCN)}
    Zhilyaeva, EI
    Shilov, GV
    Bogdanova, OA
    Lyubovskaya, RN
    Lyubovskii, RB
    Ovanesyan, NS
    Aldoshin, SM
    Train, C
    Gruselle, M
    MATERIALS SCIENCE-POLAND, 2004, 22 (04): : 565 - 569
  • [2] Crystal structure of a new organic hydrogenmonophosphate adduct [2-NH2-6-CH3-C4H3N2O]2HPO4
    Oueslati, A.
    Kefi, R.
    Ben Nasr, C.
    Lefebvre, F.
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 871 (1-3) : 49 - 58
  • [3] Crystal Structure and Spectroscopic Studies of a New Organic Dihydrogenmonophosphate [2-NH2-6-CH3-C4H3N2O]2(H2PO4)2
    Oueslati, J.
    Kefi, R.
    Lefebvre, F.
    Rzaigui, M.
    Ben Nasr, C.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (02) : 499 - 513
  • [4] Synthesis and crystal structure of Cs2[(UO2)2(C2O4)3] and Cs2[UO2(C3H2O4)2] • H2O
    Serezhkina, L. B.
    Peresypkina, E. V.
    Medvedkov, Ya A.
    Virovets, A. V.
    Serezhkin, V. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (12) : 1465 - 1469
  • [5] Crystal structure of a new organic dihydrogenomonophosphate (C6H8N3O)2(H2PO4)2
    BenHamada, L.
    Jouini, A.
    MATERIALS RESEARCH BULLETIN, 2006, 41 (10) : 1917 - 1924
  • [6] Synthesis and crystal structure of a new o-ethylphenylammonium triphosphate [2-C2H5C6H4NH3]3H2P3O10
    Smirani, W
    Ben Nasr, C
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2004, 39 (7-8) : 1103 - 1111
  • [7] Diphenylbutadiene-bridged gadolinium complex [GdCl2(THF)(3)](2) (mu-Ph2C4H4)center dot 3THF: The synthesis and crystal structure
    Emelyanova, NS
    Trifonov, AA
    Zakharov, LN
    Shestakov, AF
    Struchkov, YT
    Bochkarev, MN
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 540 (1-2) : 1 - 6
  • [8] METAL-COMPLEXES OF NEW CHIRAL TRIDENTATE LIGANDS WITH N-DONORS, P-DONORS AND S-DONORS - THE CRYSTAL-STRUCTURE OF [(S)-PH2POCH2CH(NME2)CH2CH2SCH3]W(CO)3
    FALLER, JW
    ZHANG, NJ
    CHASE, KJ
    MUSKER, WK
    AMARO, AR
    SEMKO, CM
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 468 (1-2) : 175 - 182
  • [9] Synthesis, structure and spectroscopic characterization of a new organic cation diphosphate: [2,6-(C2H5)2C6H3NH3]2H2P2O7 • 2H2O
    Akriche, S.
    Rzaigui, M.
    STRUCTURAL CHEMISTRY, 2008, 19 (05) : 827 - 831
  • [10] Synthesis, structure and spectroscopic characterization of a new organic cation diphosphate: [2,6-(C2H5)2C6H3NH3]2H2P2O7 · 2H2O
    S. Akriche
    M. Rzaigui
    Structural Chemistry, 2008, 19 : 827 - 831
12345