Graphene-Based Catalysts for Ozone Processes to Decontaminate Water

被引:27
作者
Beltran, Fernando J. [1 ]
Alvarez, Pedro M. [1 ]
Gimeno, Olga [1 ]
机构
[1] Univ Extremadura, Univ Invest Agua Cambio Climat & Sostenibilidad, Dept Ingn Quim & Quim Fis, Badajoz 06006, Spain
关键词
graphene oxide; ozone; catalytic ozonation; photocatalytic ozonation; water contaminants; PERSONAL CARE PRODUCTS; ASSISTED PHOTOCATALYTIC OZONATION; RATE CONSTANTS; WASTE-WATER; DOPED GRAPHENE; OXALIC-ACID; EMERGING CONTAMINANTS; OXIDATION PROCESSES; FUNCTIONAL-GROUPS; BISPHENOL-A;
D O I
10.3390/molecules24193438
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The use of graphene-based materials as catalysts in both ozone and ozone/radiation processes is creating interest among researchers devoted to the study of advanced oxidation processes (AOPs) for the degradation of organic pollutants in water. In this review, detailed explanations of catalytic and photocatalytic ozonation processes mediated by graphene-based materials are presented, focusing on aspects related to the preparation and characterization of catalysts, the nature of the water pollutants treated, the type of reactors and radiation sources applied, the influence of the main operating variables, catalyst activity and stability, and kinetics and mechanisms.
引用
收藏
页数:30
相关论文
共 119 条
[1]   Effect of graphene oxidation degree on the catalytic activity of graphene for ozone catalysis [J].
Ahn, Yongtae ;
Oh, Heegun ;
Yoon, Yeojoon ;
Park, Won Kyu ;
Yang, Woo Seok ;
Kang, Joon-Wun .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2017, 5 (04) :3882-3894
[2]   Synergistic Effect of O3 and H2O2 on the Visible Photocatalytic Degradation of Phenolic Compounds Using TiO2/Reduced Graphene Oxide Nanocomposite [J].
Al-Kandari, H. ;
Abdullah, A. M. ;
Al-Kandari, S. ;
Mohamed, A. M. .
SCIENCE OF ADVANCED MATERIALS, 2017, 9 (05) :739-746
[3]   Preparation and characterization of magnetic TiO2 nanoparticles and their utilization for the degradation of emerging pollutants in water [J].
Alvarez, Pedro M. ;
Jaramillo, Josefa ;
Lopez-Pinero, Francisco ;
Plucinski, Pawel K. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 100 (1-2) :338-345
[4]   THE KINETICS OF MN(II)-CATALYZED OZONATION OF OXALIC-ACID IN AQUEOUS-SOLUTION [J].
ANDREOZZI, R ;
INSOLA, A ;
CAPRIO, V ;
DAMORE, MG .
WATER RESEARCH, 1992, 26 (07) :917-921
[5]   Preparation and photocatalytic activity of TiO2-exfoliated graphite oxide composite using an ecofriendly graphite oxidation method [J].
Baldissarelli, Vanessa Zanon ;
de Souza, Thiago ;
Andrade, Luisa ;
Cappa de Oliveira, Luiz Fernando ;
Jose, Humberto Jorge ;
Peralta Muniz Moreira, Regina de Fatima .
APPLIED SURFACE SCIENCE, 2015, 359 :868-874
[6]  
Beltran F., 2004, OZONE REACTION KINET
[7]   Solar or UVA-Visible Photocatalytic Ozonation of Water Contaminants [J].
Beltran, Fernando J. ;
Rey, Ana .
MOLECULES, 2017, 22 (07)
[8]   Kinetic modelling of TOC removal in the photocatalytic ozonation of diclofenac aqueous solutions [J].
Beltran, Fernando J. ;
Aguinaco, Almudena ;
Garcia-Araya, Juan F. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 100 (1-2) :289-298
[9]   Mechanism and kinetics of sulfamethoxazole photocatalytic ozonation in water [J].
Beltran, Fernando J. ;
Aguinaco, Almudena ;
Garcia-Araya, Juan F. .
WATER RESEARCH, 2009, 43 (05) :1359-1369
[10]  
BELTRAN FJ, 1993, PROCESS SAF ENVIRON, V71, P57