Quantum-Dot-Sensitized Solar Cells

被引:791
作者
Ruhle, Sven [1 ]
Shalom, Menny [1 ]
Zaban, Arie [1 ]
机构
[1] Bar Ilan Univ, Dept Chem, Inst Nanotechnol & Adv Mat, IL-52900 Ramat Gan, Israel
关键词
electrochemistry; materials science; photochemistry; quantum dots; solar cells; BAND-EDGE MOVEMENT; CHEMICAL BATH DEPOSITION; DETAILED BALANCE LIMIT; CONVERSION EFFICIENCY; ELECTRONIC TRANSPORT; NANOCRYSTALLINE TIO2; NANOWIRE ARRAYS; SEMICONDUCTOR NANOCRYSTALS; ELECTROCHEMICAL DEPOSITION; ELECTROPHORETIC DEPOSITION;
D O I
10.1002/cphc.201000069
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Quantum-dot-sensitized solar cells (QDSCs) are a promising low-cost alternative to existing photovoltaic technologies such as crystalline silicon and thin inorganic films. The absorption spectrum of quantum dots (QDs) can be tailored by controlling their size, and QDs can be produced by low-cost methods. Nanostructures such as mesoporous films, nanorods, nanowires, nanotubes and nanosheets with high microscopic surface area, redox electrolytes and solid-state hole conductors are borrowed from standard dye-sensitized solar cells (DSCs) to fabricate electron conductor/QD monolayer/hole conductor junctions with high optical absorbance. Herein we focus on recent developments in the field of mono- and polydisperse QDSCs. Stability issues are adressed, coating methods are presented, performance is reviewed and special emphasis is given to the importance of energy-level alignment to increase the light to electric power conversion efficiency.
引用
收藏
页码:2290 / 2304
页数:15
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