Synthesis of novel polycyano-containing organic ligands via double carbanion cleavage of 1′,3′-dioxo-1′,3′-dihydrospiro[cyclopropane-1,2′-indene] derivatives

被引：8

作者：

Karpov, S. V. ^{[1
]}

Kaukov, Ya. S. ^{[1
]}

Grigor'ev, A. A. ^{[1
]}

Nasakin, O. E. ^{[1
]}

Kaukova, O. V. ^{[2
]}

Tafeenko, V. A. ^{[3
]}

机构：

[1] IN Ulyanov Chuvash State Univ, Dept Chem & Pharm, Moskovskii Pr 15, Cheboksary 428015, Russia

[2] Chuvash State Agr Acad, K Marx St 29, Cheboksary 428015, Russia

[3] Moscow MV Lomonosov State Univ, Dept Chem, Leninskiye Gory 1-3, Moscow 119991, Russia

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 15期

关键词：

MAGNETIC-PROPERTIES; CYANOCARBANION;

D O I：

10.1039/c6ob00092d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel fast, convenient and inexpensive synthesis of 1',3'- dioxo-1',3'-dihydrospiro[cyclopropane -1,2'-in de ne] -2,2,3,3-tetracarbonitrile and dimethyl 2,3-dicyano-r,3'-dioxo-r,3'-dihydrospiro[cyclopropane1,2`-indene]-2,3-dicarboxylate is reported. These compounds undergo double carbanion cleavage under the action of alcohols resulting in the formation of stable salts, containing new allylic-type anions with potential application in organic electronics and as ionic liquid components.

引用

页码：3758 / 3764

页数：7