Interaction of alkali metals with perylene-3,4,9,10-tetracarboxylic-dianhydride thin films studied by IR spectroscopy

被引：17

作者：

Heimer, K. ^{[1
]}

Wuesten, J. ^{[1
]}

Lach, S. ^{[1
]}

Ziegler, Ch. ^{[1
]}

机构：

[1] Univ Kaiserslautern, Dept Phys, D-67663 Kaiserslautern, Germany

来源：

JOURNAL OF CHEMICAL PHYSICS | 2007年 / 126卷 / 16期

关键词：

D O I：

10.1063/1.2722748

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In order to clarify the doping behavior of different alkali metals in perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), Fourier transform infrared spectra of PTCDA thin films doped with sodium, potassium, and cesium were measured and compared. Furthermore the vibrational properties were calculated using density-functional theory and these calculated vibrational frequencies were assigned to the experimental IR modes of the thin films. (c) 2007 American Institute of Physics.

引用

页数：5

共 27 条

[1] MOLECULAR-ORGANIZATION IN PERYLENETETRACARBOXYLIC DIANHYDRIDE FILMS [J].

AKERS, K ;

AROCA, R ;

HOR, AM ;

LOUTFY, RO .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (11) :2954-2959

[2] IR and SFM study of PTCDA thin films on different substrates [J].

Berger, S ;

Heimer, K ;

Mack, HG ;

Ziegler, C .

APPLIED SURFACE SCIENCE, 2005, 252 (01) :81-84

[3] Experimental and theoretical studies of the pi-electronic structure of conjugated polymers and the low work function metal/conjugated polymer interaction [J].

Fahlman, M ;

Bredas, JL ;

Salaneck, WR .

SYNTHETIC METALS, 1996, 78 (03) :237-246

[4] Organic-inorganic semiconductor devices and 3, 4, 9, 10 perylenetetracarboxylic dianhydride: an early history of organic electronics [J].

Forrest, SR .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (38) :S2599-S2610

[5] High intercalation levels in lithium perylene stoichiometric compounds [J].

Friedlein, R ;

Crispin, X ;

Pickholz, M ;

Keil, M ;

Stafström, S ;

Salaneck, WR .

CHEMICAL PHYSICS LETTERS, 2002, 354 (5-6) :389-394

[6] Preparation and characterization of single-phase potassium-doped PTCDA thin films [J].

Fuentes, GG ;

Knupfer, M .

PHYSICAL REVIEW B, 2004, 70 (23) :1-4

[7] Harmonic frequency scaling factors for Hartree-Fock, S-VWN, B-LYP, B3-LYP, B3-PW91 and MP2 with the Sadlej pVTZ electric property basis set [J].

Halls, MD ;

Velkovski, J ;

Schlegel, HB .

THEORETICAL CHEMISTRY ACCOUNTS, 2001, 105 (06) :413-421

[8]

Horowitz G, 1998, ADV MATER, V10, P365, DOI 10.1002/(SICI)1521-4095(199803)10:5<365::AID-ADMA365>3.0.CO

[9]

2-U

[10] Electrical conductivity and electronic structure of potassium doped PTCDA [J].

Iwasaki, K ;

Umishita, K ;

Sakata, M ;

Hino, S .

SYNTHETIC METALS, 2001, 121 (1-3) :1395-1396

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