Formation of a metal-organic framework with high gas uptakes based upon amino-decorated polyhedral cages

被引：20

作者：

Yun, Ruirui ^{[1
]}

Cui, Ranran ^{[1
]}

Qian, Fujun ^{[1
]}

Cao, Xiaoyan ^{[1
]}

Luo, Shizhong ^{[1
]}

Zheng, Baishu ^{[2
]}

机构：

[1] Anhui Normal Univ, Anhui Key Lab Funct Mol Solids, Anhui Lab Mol Based Mat,Minist Educ, Coll Chem & Mat Sci,Key Lab Funct Mol Solids, Wuhu 241000, Peoples R China

[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China

来源：

RSC ADVANCES | 2015年 / 5卷 / 04期

关键词：

CARBON-DIOXIDE CAPTURE; SURFACE-AREA; LINKERS;

D O I：

10.1039/c4ra14607g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new three-dimensional metal-organic framework 1 was solvothermally synthesized by 1,2,4-triazole and 2-aminoterephthalic acid, and structurally characterized. 1 features a three-dimensional structure with one-dimensional pores along the c axis of 6 x 6 angstrom(2). Activated 1 exhibits an H-2 uptake capacity at 77 K. Importantly, it shows excellent enthalpy of CO2 (35 kJ mol(-1)) and methane (24 kJ mol(-1)), compared to previous porous materials.

引用

页码：2374 / 2377

页数：4

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