The Persistence of Inhibition of Copper Corrosion in Tap Water

被引:18
作者
Burstein, G. T. [1 ]
Bi, H. [1 ]
Kawaley, G. [2 ]
机构
[1] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England
[2] Mitsubishi Elect R&D Ctr Europe BV, 17 Firth Rd, Livingston EH54 5DJ, Scotland
关键词
Copper corrosion; Pitting; Inhibitor; Tap water; Cyclic Voltammetry; ELECTROCHEMICAL NOISE-ANALYSIS; LONG-TERM IMMERSION; CHLORIDE SOLUTION; SURFACE-ANALYSIS; FILMS; BENZOTRIAZOLE; XPS; 2-MERCAPTOBENZIMIDAZOLE; 2-MERCAPTOBENZOXAZOLE; 1,2,3-BENZOTRIAZOLE;
D O I
10.1016/j.electacta.2015.12.203
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A method is presented to test the persistence of inhibition of corrosion of copper in previously inhibited tap water. Cyclic voltammetry (CV) sweeps on copper were carried out in tap water both in the presence and in the absence of inhibitor to examine the state of passivity and of breakdown leading to localised corrosion of the metal in tap water in order to investigate the persistence of inhibitor. The results show that after prior inhibition and re-immersion in inhibitor-free tap water, inhibition is still observed and persists through several further potential cycles. These novel observations describe the persistence of the inhibitor on the surface after the supply of the inhibitor has been removed. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:247 / 255
页数:9
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