Spectroscopic Investigation of the Chemical Polymerization of Aniline with FeCl3 in Acetonitrile

被引：0

作者：

Uzun, Sultan ^{[1
]}

Can, Muzaffer ^{[1
]}

机构：

[1] Gaziosmanpasa Univ, Dept Chem, TR-60250 Tokat, Turkey

来源：

ASIAN JOURNAL OF CHEMISTRY | 2010年 / 22卷 / 02期

关键词：

Conducting polymers; Polyaniline; Chemical polymerization; Oxidant effect; FeCl3; CONDUCTING POLYMERS; POLYPYRROLE; STABILITY;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical polymerization of aniline with anhydrous ferric chloride (FeCl3) in non-acidic medium was investigated using experimental methods such as conductivity measurements, thermal analysis (TGA-DTG) UV-visible and FTIR spectroscopy. As well known, FeCl3 is a Lewis acid, which can form complex with aniline. In the chemical polymerization, these properties of FeCl3 are not taken into consideration. The studies indicate that FeCl3 behaves as a Lewis acid, a substance, forming complex or oxidant material depending of the acidity of medium.

引用

页码：1331 / 1338

页数：8

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