High performance nanoporous carbon from mulberry leaves (Morus alba L. ) residues via microwave treatment assisted hydrothermal-carbonization for methyl orange adsorption: Kinetic, equilibrium and thermodynamic studies

被引:15
作者
Siraorarnroj, Siwat [1 ]
Kaewtrakulchai, Napat [2 ]
Fuji, Masayoshi [3 ]
Eiad-ua, Apiluck [1 ]
机构
[1] King Mongkuts Inst Technol Ladkrabang, Coll Mat Innovat & Technol, Bangkok 10520, Thailand
[2] Kasetsart Univ, Kasetsart Agr & Agroind Prod Improvement Inst, Bangkhen, Bangkok 10900, Thailand
[3] Nagoya Inst, Adv Ceram Ctr, Technol, Tajimi, Gifu, Japan
来源
MATERIALIA | 2022年 / 21卷
关键词
Nanoporous carbons; Mulberry leaves residues; Hydrothermal carbonization; Methyl orange; Adsorption; MESOPOROUS-ACTIVATED CARBON; SURFACE-AREA; BLUE; REMOVAL; WASTE; ISOTHERM; BIOCHAR; BIOMASS; STONES; SEED;
D O I
10.1016/j.mtla.2021.101288
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
High performance nanoporous carbons were directly prepared from mulberry leaves (Morus alba L .) residues by the hydrothermal-carbonization with chemical reagent combined the microwave-assisted treatment. The as-purified ML porous carbon (MPC) was successfully applied for the adsorption of methyl orange, which is one of crucial waste-water pollutants left from an industrial sector. The MPC sample obtained from the hydrothermal process (200 degrees C, 12 h) using an activation of 15 wt% NaOH (700 degrees C, 2 h), and combined with microwave treatment at 700 W for 6 min, specifically exhibited micropores and mesopores in the MPC morphological structure. Accordingly, the highest SBET was approximately 791.79 m(2)/g with the total pore volume of 0.495 cm(3)/g. Moreover, the adsorption performance test of MPC was conducted by the shaking unit using 100 ppm methyl orange concentration. The MPC showed the highest methyl orange-adsorption uptake of 99% at 30 degrees C under an ambient pressure (1 atm). The development of mulberry leaves (Morus alba L .) residues into porous carbon exhibited a great attention for dyes adsorption with a rapid adsorption kinetic, and excellent adsorption capacity, which are a promising-characteristics for practical waste-water adsorption experiments.
引用
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页数:12
相关论文
共 57 条
[1]   Removal of antibiotics from water and waste milk by ozonation: kinetics, byproducts, and antimicrobial activity [J].
Alsager, Omar A. ;
Alnajrani, Mohammed N. ;
Abuelizz, Hatem A. ;
Aldaghmani, Ibrahim A. .
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2018, 158 :114-122
[2]   Modelling and Interpretation of Adsorption Isotherms [J].
Ayawei, Nimibofa ;
Ebelegi, Augustus Newton ;
Wankasi, Donbebe .
JOURNAL OF CHEMISTRY, 2017, 2017
[3]   A packed bed membrane reactor for production of biodiesel using activated carbon supported catalyst [J].
Baroutian, Saeid ;
Aroua, Mohamed K. ;
Raman, Abdul Aziz A. ;
Sulaiman, Nik M. N. .
BIORESOURCE TECHNOLOGY, 2011, 102 (02) :1095-1102
[4]   Influence of Pyrolysis Temperatures on FTIR Analysis, Nutrient Bioavailability, and Agricultural use of Poultry Manure Biochars [J].
Bavariani, Mokhtar Zolfi ;
Ronaghi, Abdolmajid ;
Ghasemi, Reza .
COMMUNICATIONS IN SOIL SCIENCE AND PLANT ANALYSIS, 2019, 50 (04) :402-411
[5]   Preparation and characterization of activated carbon from date stones by physical activation with steam [J].
Bouchelta, Chafia ;
Medjram, Mohamed Salah ;
Bertrand, Odile ;
Bellat, Jean-Pierre .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2008, 82 (01) :70-77
[6]   Pyrolysis vs. hydrothermal carbonization: Understanding the effect of biomass structural components and inorganic compounds on the char properties [J].
Correa, Catalina Rodriguez ;
Hehr, Tobias ;
Voglhuber-Slavinsky, Ariane ;
Rauscher, Yannik ;
Kruse, Andrea .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2019, 140 :137-147
[7]  
Dada A.O., 2012, Journal of Applied Chemistry, V3, P38, DOI [10.9790/5736-0313845, DOI 10.9790/5736-0313845]
[8]   The potential feasibility for soil improvement, based on the properties of biochars pyrolyzed from different feedstocks [J].
Dai, Zhongmin ;
Meng, Jun ;
Muhammad, Niaz ;
Liu, Xingmei ;
Wang, Haizhen ;
He, Yan ;
Brookes, Philip C. ;
Xu, Jianming .
JOURNAL OF SOILS AND SEDIMENTS, 2013, 13 (06) :989-1000
[9]  
Danish M., 2018, Bioresour. Technol. Reports, V3, P127, DOI [DOI 10.1016/J.BITEB.2018.07.007, 10.1016/j.biteb.2018.07.007]
[10]  
Danish M, 2013, BIORESOURCES, V8, P4323