A Tetrathiafulvalene-Based Electroactive Covalent Organic Framework

被引：160

作者：

Ding, Huimin ^{[1
]}

Li, Yonghai ^{[2
]}

Hu, Hui ^{[1
]}

Sun, Yimeng ^{[2
]}

Wang, Jianguo ^{[2
]}

Wang, Caixing ^{[1
]}

Wang, Cheng ^{[1
]}

Zhang, Guanxin ^{[2
]}

Wang, Baoshan ^{[1
]}

Xu, Wei ^{[2
]}

Zhang, Deqing ^{[2
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Peoples R China

[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Organ Solids Lab, Beijing 100190, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 45期

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

conducting materials; covalent organic frameworks; electron donor; microporous materials; tetrathiafulvalene; CAGE; SYSTEMS;

D O I：

10.1002/chem.201405330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-dimensional covalent organic frameworks (2D COFs) provide a unique platform for the molecular design of electronic and optoelectronic materials. Here, the synthesis and characterization of an electroactive COF containing the well-known tetrathiafulvalene (TTF) unit is reported. The TTF-COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and shows high thermal stability and permanent porosity. The presence of TTF units endows the TTF-COF with electron-donating ability, which is characterized by cyclic voltammetry. In addition, the open frameworks of TTF-COF are amenable to doping with electron acceptors (e.g., iodine), and the conductivity of TTF-COF bulk samples can be improved by doping. Our results open up a reliable route for the preparation of well-ordered conjugated TTF polymers, which hold great potential for applications in fields from molecular electronics to energy storage.

引用

页码：14614 / 14618

页数：5

共 46 条

[31] Straightforward access to aryl-substituted tetrathiafulvalenes by palladium-catalysed direct C-H arylation and their photophysical and electrochemical properties [J].

Mitamura, Yukihiro ;

Yorimitsu, Hideki ;

Oshima, Koichiro ;

Osuka, Atsuhiro .

CHEMICAL SCIENCE, 2011, 2 (10) :2017-2021

[32] High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal-Organic Framework [J].

Narayan, Tarun C. ;

Miyakai, Tomoyo ;

Seki, Shu ;

Dinca, Mircea .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (31) :12932-12935

[33] Reinvestigation of the MII (M = Ni, Co)/TetraThiafulvaleneTetraCarboxylate System Using High-Throughput Methods: Isolation of a Molecular Complex and Its Single-Crystal-to-Single-Crystal Transformation to a Two-Dimensional Coordination Polymer [J].

Nguyen, Thi Le Anh ;

Devic, Thomas ;

Mialane, Pierre ;

Riviere, Eric ;

Sonnauer, Andreas ;

Stock, Norbert ;

Demir-Cakan, Rezan ;

Morcrette, Mathieu ;

Livage, Carine ;

Marrot, Jerome ;

Tarascon, Jean-Marie ;

Ferey, Gerard .

INORGANIC CHEMISTRY, 2010, 49 (22) :10710-10717

[34] Supramolecular conducting nanowires from organogels [J].

Puigmarti-Luis, Josep ;

Laukhin, Vladimir ;

del Pino, Angel Perez ;

Vidal-Gancedo, Jose ;

Rovira, Concepcio ;

Laukhina, Elena ;

Amabilino, David B. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (1-2) :238-241

[35] A 2D Mesoporous Imine-Linked Covalent Organic Framework for High Pressure Gas Storage Applications [J].

Rabbani, Mohammad Gulam ;

Sekizkardes, Ali Kemal ;

Kahveci, Zafer ;

Reich, Thomas E. ;

Ding, Ransheng ;

El-Kaderi, Hani M. .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (10) :3324-3328

[36] A tetrathiafulvalene-functionalized schiff base macrocycle: synthesis, electrochemical, and photophysical properties [J].

Ran, Ying-Fen ;

Blum, Carmen ;

Liu, Shi-Xia ;

Sanguinet, Lionel ;

Levillain, Eric ;

Decurtins, Silvio .

TETRAHEDRON, 2011, 67 (09) :1623-1627

[37] Lattice Expansion of Highly Oriented 2D Phthalocyanine Covalent Organic Framework Films [J].

Spitler, Eric L. ;

Colson, John W. ;

Uribe-Romo, Fernando J. ;

Woll, Arthur R. ;

Giovino, Marissa R. ;

Saldivar, Abraham ;

Dichtel, William R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (11) :2623-2627

[38]

Spitler EL, 2010, NAT CHEM, V2, P672, DOI [10.1038/NCHEM.695, 10.1038/nchem.695]

[39]

Wan S., 2008, Angew. Chem, V120, P8958, DOI [DOI 10.1002/ANGE.200803826, 10.1002/ange.200803826]

[40] A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework [J].

Wan, Shun ;

Guo, Jia ;

Kim, Jangbae ;

Ihee, Hyotcherl ;

Jiang, Donglin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (46) :8826-8830

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